Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 81, Issue 23, Pages 12031-12037Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b02322
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Funding
- National Natural Science Foundation of China [21372219]
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A ruthenium-catalyzed intermolecular [3 + 2] cycloaddition of 2H-azirines and activated alkynes is reported, which provides polysubstituted pyrroles in moderate to good yields. This approach features a C-N bond cleavage of 2H-azirines by a ruthenium catalyst. The results of this study would provide a complementary method to synthesize polysubstituted pyrroles from the known 2H-azirine approaches and advance 2H-azirine chemistry.
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