Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 81, Issue 3, Pages 1000-1005Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b02564
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Funding
- National Science Foundation of China [21202049]
- Recruitment Program of Global Experts (1000 Talents Plan)
- Fujian Hundred Talents Plan
- Program of Innovative Research Team of Huaqiao University [Z14X0047]
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A palladium-catalyzed arylboration of norbornene or norbomadiene with aryl halides and bis(pinacolato)diboron has been disclosed. Mechanistic studies suggest that the reaction proceeds under a Catellani-type coupling to render versatile multifunctionalized alkylboranes in good yields. This reaction is complementary to the existing methods and is well tolerable with a variety of functional groups and readily scaled-up to a gram scale without deteriorating the yield.
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