Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 81, Issue 14, Pages 5886-5894Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b00593
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Funding
- CSIR [BSC-0108, HCP-0001]
- UGC
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Herein, we report a simple and metal-free method for the synthesis of N-azine sulfoximines by the nucleophilic substitution of azine N-oxides with NH-sulfoximines. The present method works at room temperature with wide functional group compatibility and gives several unprecedented N-azine sulfoximines. The reaction conditions were also found suitable with enantiopure substrates and furnished products without any racemization. It also finds an application in the sulfoximination of azine-based functional molecules such as 2,2'-bipyridine, 1,10-phenanthroline, and quinine.
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