Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 81, Issue 9, Pages 3967-3974Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b00553
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Funding
- Platform Project for Supporting in Drug Discovery and Life Science Research (Platform for Drug Discovery, Informatics, and Structural Life Science) from the Ministry of Education, Culture, Sports, Science and Technology (MEXT)
- Japan Agency for Medical Research and Development (AMED)
- Grants-in-Aid for Scientific Research [15K18833] Funding Source: KAKEN
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A three-step synthetic method for the preparation of fluoranthenes, involving Miura's intermolecular C-H arylation, nonaflation, and intramolecular C-H arylation, has been developed. Various 1-naphthols and haloarenes were successfully used as substrates. Reaction conditions that afford high site selectivity have been developed for the intramolecular C-H arylation step.
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