Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 81, Issue 17, Pages 8070-8076Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b01466
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Funding
- Priority Academic Program for the Development of Jiangsu Higher Education Institutions
- Project of Scientific and Technologic Infrastructure of Suzhou [SZS201207]
- National Natural Science Foundation of China [21072143]
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The first utility of praseodymium as a mediating metal in the Barbier reaction of carbonyl compounds with allyl halides was reported in this paper. In contrast to the traditional metal-mediated or catalyzed Barbier reactions, exclusive a adducts were obtained in this one-pot reaction with a broad scope of substrates and feasible reaction conditions.
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