Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 81, Issue 19, Pages 8858-8866Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b01555
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Funding
- National 973 Program [2015CB856600]
- NSFC [21472162]
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An iminopyridine cobalt dichloride complex was synthesized and demonstrated as an effective precatalyst for hydrosilylation/cyclization of 1,6-enynes with silanes. Various functional groups such as amine, free aniline, ester, ether, cyano, halide, trifluoromethyl, and heterocycle were tolerated to afford a variety of silicon-containing compounds. The reaction could be scaled up to afford products on the gram scale which could undergo further derivatizations. A primary mechanism was proposed based on analysis of side products and a deuterated experiment.
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