Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 81, Issue 17, Pages 7963-7969Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b01254
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Funding
- Doheny Foundation
- Farrell Family
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1151092] Funding Source: National Science Foundation
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The copper-catalyzed etherification of ortho-borylated benzylic amines with phenols has been achieved to provide biaryl ethers that are prevalent in biologically active compounds. A variety of substitution patterns on the aryl boronate ester and the phenol are tolerated under the reaction conditions, providing moderate to high yields. A competition reaction between phenol and aniline revealed condition-dependent selectivity in which the phenol could be highly favored over the aniline.
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