4.7 Article

Ligand-Promoted Rh(III)-Catalyzed Coupling of Aryl C-H Bonds with Arylboron Reagents

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 81, Issue 8, Pages 3416-3422

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b00083

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Funding

  1. National Natural Science Foundation of China [21201100, 21331002]

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Rhodium(III)-catalyzed C-H arylation of arenes with phenylboronic acid pinacol esters has been achieved using a readily removable N-pentafluorophenylbenzamide directing group for the first time. The use of a bidentate phosphine ligand (Binap) significantly increased the yield of the cross-coupling of C-H bonds with organoboron reagents.

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