4.7 Article

Novel hybrid materials based on mesoporous Gamma-Alumina@ Riboflavin@ vanadium for biodiesel production

Related references

Note: Only part of the references are listed.
Review Chemistry, Multidisciplinary

Porous organic-inorganic hybrid materials for catalysis, energy and environmental applications

Sayantan Chongdar et al.

Summary: The introduction of organic functionalities into porous inorganic materials enhances flexibility and hydrophobicity while providing additional metal binding sites, greatly expanding the application potential in areas such as adsorption, sensing, energy storage, and environmental research.

CHEMICAL COMMUNICATIONS (2022)

Article Energy & Fuels

Possibility of Advanced Modified-Silica-Based Porous Materials Utilisation in Water Adsorption Processes-A Comparative Study

Karol Sztekler et al.

Summary: Due to high risk of power outages, heat-driven adsorption chillers are gaining attention. In order to improve their efficiency, new adsorbents need to be produced and tested. In this study, four newly developed silica-based porous materials were tested and compared with commonly used silica gel. Thermal properties similar to silica gel were found in metal organic silica (MOS) nanocomposites analyzed in this study, but with higher water adsorption capacity.

ENERGIES (2022)

Article Chemistry, Physical

Chemistry-Encoded Convolutional Neural Networks for Predicting Gaseous Adsorption in Porous Materials

Ting-Hsiang Hung et al.

Summary: In this study, a chemistry-encoded convolutional neural network model is proposed to predict gaseous adsorption properties in diverse metal-organic frameworks. The model shows superior prediction accuracy when trained and tested on approximately 10,000 MOF structures computed via molecular simulations.

JOURNAL OF PHYSICAL CHEMISTRY C (2022)

Article Food Science & Technology

The Layered Encapsulation of Vitamin B2 and β-Carotene in Multilayer Alginate/Chitosan Gel Microspheres: Improving the Bioaccessibility of Vitamin B2 and β-Carotene

Peilong Liao et al.

Summary: This research highlights the potential of alginate multilayered gel microspheres for layered encapsulation and simultaneous delivery of vitamin B-2 and beta-carotene. Chitosan was used to enhance the stability and controlled release ability of the gel microspheres. The results showed that the multilayered gel microspheres had pH response characteristics and excellent thermal stability. The concentration of sodium alginate and the number of layers had significant effects on the mechanical properties and particle size of the gel microspheres. Fourier-transform infrared spectroscopy and X-ray diffraction analyses confirmed the encapsulation of vitamin B-2 and beta-carotene within the gel microspheres. The simultaneous encapsulation of these two compounds improved their bioaccessibility and bioavailability.

FOODS (2022)

Article Materials Science, Multidisciplinary

Preparation, characterization and evaluation of x-MoO3/Al-SBA-15 catalysts for biodiesel production

Joyce S. B. Figueiredo et al.

Summary: This study evaluated the influence of MoO3 content and reaction time on the biodiesel yield from soybean oil and methanol. The results showed that the catalyst 10%MoO3/Al-SBA-15 achieved an average biodiesel yield of 96% under the reaction conditions of 20:1 methanol/soybean oil molar ratio, 3 wt% catalyst loading, at 150 degrees C for 3 hours.

MATERIALS FOR RENEWABLE AND SUSTAINABLE ENERGY (2022)

Article Chemistry, Applied

Nanostructured KIT-6 materials functionalized with sulfonic groups for catalytic purposes

Agata Wawrzynczak et al.

Summary: In this study, ordered nanostructured KIT-6 silica with different numbers of sulfonic groups were synthesized. The amount of the functional group precursor used affected the structural and textural parameters of the synthesized materials. The samples modified by grafting exhibited a stable mesoporous structure, while the ones synthesized by co-condensation showed characteristics of KIT-6 materials. The developed synthesis procedures yielded potential solid acid catalysts with desirable catalytic performances.

CATALYSIS TODAY (2022)

Article Engineering, Multidisciplinary

Enzymolysis-treated wood-derived hierarchical porous carbon for fluorescence-functionalized phase change materials

Yaqiong Li et al.

Summary: The current obstacles hindering the development and industrial application of phase change materials (PCMs) include low thermal conductivity, high cost, leakage, and poor mechanical performance. This study aims to enhance the thermal conductivity and power capacity of PCMs by using abundant biomass-derived carbon as supports. Cellulase is used to hydrolyze cellulose in wood and create micropores, which leads to effective construction of adsorption sites during the subsequent pyrolysis process. The resulting hierarchical porous carbon infiltrates polyethylene glycol (PEG) and enhances crystallization. This strategy combines good mechanical performance, high energy storage capacity, anisotropic thermal conductivity, and improved thermal stability. Furthermore, the composite PCMs loaded with carbon quantum dots (CQDs) integrate fluorescent function and thermal energy storage, providing potential applications in specific equipment.

COMPOSITES PART B-ENGINEERING (2022)

Article Energy & Fuels

Ag modification of SBA-15 and MCM-41 mesoporous materials as sorbents of thiophene

Yang Liu et al.

Summary: This paper investigates the adsorption performance of silver-modified mesoporous materials in removing thiophenic compounds. The results show that the adsorption of thiophene by the sorbents involves S-Ag and pi complexation reactions, and the adsorption efficiency is greatly affected by benzene. XPS analysis reveals that silver interacts strongly with the carrier and forms Ag-O-Si bonds as the active centers for thiophenic compounds. The Mulliken charges of sulfur atoms have an impact on the interactions between silver and thiophene sulfur compounds.
Article Green & Sustainable Science & Technology

Molybdenum and zirconium oxides supported on KIT-6 silica: A recyclable composite catalyst for one-pot biodiesel production from simulated low-quality oils

Quan Wang et al.

Summary: The development of feasible and ecofriendly processes for biodiesel production is of great importance for green chemistry and sustainable development. In this study, a one-pot heterogeneous catalytic system using MoO3/ZrO2/KIT-6 catalyst was developed for the synthesis of high-performance biodiesel. The optimized catalyst showed excellent tolerance and reusability.

RENEWABLE ENERGY (2022)

Article Green & Sustainable Science & Technology

Magnetic reusable acid-base bifunctional Co doped Fe2O3-CaO nanocatalysts for biodiesel production from soybean oil and waste frying oil

Shaige Xia et al.

Summary: In this study, acid-base bi-functional Co doped Fe2O3-CaO nanocatalysts were prepared and optimized for biodiesel production, showing enhanced catalytic activity and FFA resistance. The biodiesel yield from soybean oil and WFO was significantly improved, along with better stability and reusability of the catalyst.

RENEWABLE ENERGY (2022)

Article Chemistry, Physical

Photo-Induced Preparation of Ag@MOF-801 Composite Based Heterogeneous Nanocatalyst for the Production of Biodiesel

Osamah M. Alduhaish et al.

Summary: Hybrid materials based on metal-organic frameworks and nanoparticles have shown excellent efficiency and synergistic effects in heterogeneous catalysis. In this study, a simple and eco-friendly photocatalytic method was used to fabricate Zr-containing MOF-801 and a silver nanoparticle-based hybrid. The resulting hybrid material served as a highly efficient catalyst for biodiesel production.

CATALYSTS (2022)

Article Engineering, Chemical

Biodiesel Production from Waste Animal Fat by Transesterification Using H2SO4 and KOH Catalysts: A Study of Physiochemical Properties

Nasim Hasan et al.

Summary: This study focuses on using waste animal fat as a feedstock for biodiesel production, and optimizes the catalysts and process conditions. The results show that using sulfuric acid as a catalyst can achieve a higher biodiesel yield. This study not only provides an environmentally friendly solution to reduce atmospheric pollution but also presents a commercial alternative to mitigate the ecological impact caused by waste animal fat.

INTERNATIONAL JOURNAL OF CHEMICAL ENGINEERING (2022)

Review Thermodynamics

Water Vapor Adsorption by Porous Materials: From Chemistry to Practical Applications

Abdelhamid Metrane et al.

Summary: This Review provides an overview of water adsorption studies on different hydrolytically stable porous solids and analyzes the influence of their structural features on adsorption behavior. The prospects of practical deployment of these adsorbents in specific sectors are evaluated, and the challenges in developing efficient water vapor adsorbents are discussed.

JOURNAL OF CHEMICAL AND ENGINEERING DATA (2022)

Article Multidisciplinary Sciences

Efficient biodiesel production from oleic and palmitic acid using a novel molybdenum metal-organic framework as efficient and reusable catalyst

Arash Ghorbani-Choghamarani et al.

Summary: In this study, a metal-organic framework catalyst based on molybdenum and piperidine-4-carboxylic acid was synthesized and employed for biodiesel production. The catalyst exhibited high activity, thermal stability, and reusability.

SCIENTIFIC REPORTS (2022)

Article Chemistry, Multidisciplinary

Synthesis and Application of Nano Vanadium-Oxo Pyridiniumporphyrazinato Sulfonic Acid for Synthesizing Pyrazole and Dihydropyrano[2,3]pyrazole Derivatives

Mahtab Moeinimehr et al.

Summary: This study presents the design and synthesis of a nano-N-sulfonated phthalocyanine molten salt catalyst for synthesizing pyrazole and dihydropyrano [2,3] pyrazole derivatives. After multiple recycling and reapplication, the catalyst maintains its catalytic activity.

CHEMISTRYSELECT (2022)

Review Materials Science, Multidisciplinary

Single-atom catalysts supported on ordered porous materials: Synthetic strategies and applications

Kaiwen Xue et al.

Summary: Single-atom catalysts (SACs) have drawn extensive attention due to their high catalytic activity and selectivity, high utilization of metal atoms, and cost reduction. Ordered porous materials (OPMs) serve as promising carriers for stabilizing single atoms by tuning their geometric and electronic structures through interactions, enhancing the catalytic activity. The development of SACs based on OPMs such as zeolites, metal-organic frameworks, and ordered mesoporous materials has been rapidly advancing, providing opportunities and challenges for developing novel catalysts with superior catalytic performances in the future.

INFOMAT (2022)

Article Chemistry, Applied

Effect of biofuel- and lube oil-originated sulfur and phosphorus on the performance of Cu-SSZ-13 and V2O5-WO3/TiO2 SCR catalysts

Sandra Dahlin et al.

Summary: Two different SCR catalysts showed varying performance in capturing phosphorus and sulfur from biodiesel exhausts, with sulfur mainly affecting the Cu-SSZ-13 catalyst at lower temperatures. The use of an oxidation catalyst upstream can protect the SCR catalysts from phosphorus poisoning.

CATALYSIS TODAY (2021)

Article Chemistry, Multidisciplinary

Role of Framework-Carrier Interactions in Proton-Conducting Crystalline Porous Materials

Arindam Gupta et al.

Summary: Studies focusing on proton conductivity in crystalline porous materials, particularly metal-organic frameworks and coordination polymers, have attracted significant attention due to their potential applications in fuel cell membranes. These materials offer well-defined structural features, easy synthesis routes, and functional channels for proton transport. Research in this area emphasizes understanding the fundamental principles of proton conduction and various design strategies for controlling framework-carrier interactions.

CRYSTAL GROWTH & DESIGN (2021)

Article Multidisciplinary Sciences

Design and synthesis of Fe3O4@SiO2@KIT-6@DTZ-Pd0 as a new and efficient mesoporous magnetic catalyst in carbon-carbon cross-coupling reactions

Zahra Moradi et al.

Summary: A new type of mesoporous material based on KIT-6 has been introduced in this study, which combines magnetic Fe3O4 nanoparticles and mesoporous silica KIT-6 to obtain magnetic mesoporous MNPs. This magnetic mesoporous catalyst has been successfully applied in various carbon-carbon cross-coupling reactions and characterized by different techniques.

SCIENTIFIC REPORTS (2021)

Review Chemistry, Multidisciplinary

Porous Silicon Carbide (SiC): A Chance for Improving Catalysts or Just Another Active-Phase Carrier?

Giulia Tuci et al.

Summary: The article highlights the gap between catalyst active phases and functional carriers, emphasizing the advantages and future potential of silicon carbide (SiC) as a carrier material in heterogeneous catalysis.

CHEMICAL REVIEWS (2021)

Article Thermodynamics

Three-phase lag model of thermo-elastic interaction in a 2D porous material due to pulse heat flux

Aatef Hobiny et al.

INTERNATIONAL JOURNAL OF NUMERICAL METHODS FOR HEAT & FLUID FLOW (2020)

Article Green & Sustainable Science & Technology

Biodiesel production from esterification of oleic acid by a sulfonated magnetic solid acid catalyst

Yi-Tong Wang et al.

RENEWABLE ENERGY (2019)

Article Engineering, Electrical & Electronic

Green synthesis of amorphous and gamma aluminum oxide nanoparticles by tragacanth gel and comparison of their photocatalytic activity for the degradation of organic dyes

Kobra Atrak et al.

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS (2018)

Article Chemistry, Physical

Catalytic performance of binary and ternary oxovanadium complexes of dipyridinyl-urea in (ep)oxidation of cis-cyclooctene and 1-octene

Mohamed Shaker S. Adam et al.

REACTION KINETICS MECHANISMS AND CATALYSIS (2018)

Proceedings Paper Engineering, Industrial

Physicochemical Properties of Ni-Mo/γ-Al2O3 Catalysts Synthesized via Sonochemical Method

Mariam Ameen et al.

PROCEEDING OF 4TH INTERNATIONAL CONFERENCE ON PROCESS ENGINEERING AND ADVANCED MATERIALS (ICPEAM 2016) (2016)

Review Chemistry, Inorganic & Nuclear

Vanadium-phosphatase complexes: Phosphatase inhibitors favor the trigonal bipyramidal transition state geometries

Craig C. McLauchlan et al.

COORDINATION CHEMISTRY REVIEWS (2015)

Article Chemistry, Physical

Switchable release and recovery of nanoparticles via a Pickering-emulsion-templated porous carrier

Ye Hua et al.

JOURNAL OF MATERIALS CHEMISTRY A (2013)

Article Thermodynamics

Biodiesel production over copper vanadium phosphate

Lei Chen et al.

ENERGY (2011)

Article Chemistry, Multidisciplinary

Synthesis, Characterization and Catalytic Activity of Two Novel cis-Dioxovanadium(V) Complexes: [VO2(L)] and [VO2(HLox)]

Natalia M. L. Silva et al.

JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY (2011)

Article Chemistry, Physical

Vanadyl acetylacetonate anchored onto amine-functionalised clays and catalytic activity in the epoxidation of geraniol

Clara Pereira et al.

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL (2008)

Article Materials Science, Multidisciplinary

Simple synthesis of mesoporous alumina thin films

Lijuan Wan et al.

MATERIALS LETTERS (2008)

Article Chemistry, Applied

Tailored mesoporous alumina prepared from different aluminum alkoxide precursors

M. May et al.

JOURNAL OF POROUS MATERIALS (2007)

Article Chemistry, Multidisciplinary

Thermally stable nanocrystalline gamma-alumina layers with highly ordered 3D mesoporosity

M Kuemmel et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2005)

Article Agricultural Engineering

Integrated biodiesel production:: a comparison of different homogeneous catalysts systems

G Vicente et al.

BIORESOURCE TECHNOLOGY (2004)

Review Oncology

Vanadium in cancer treatment

AM Evangelou

CRITICAL REVIEWS IN ONCOLOGY HEMATOLOGY (2002)

Article Chemistry, Inorganic & Nuclear

Chemistry and insulin-mimetic properties of bis(acetylacetonate)oxovanadium(IV) and derivatives

SS Amin et al.

INORGANIC CHEMISTRY (2000)