Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 26, Issue 8, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202201493
Keywords
allylsulfones; C-H activation; one-pot sequential reactions; palladium catalysis; sulfonylation
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Two previously unknown protocols for Pd-catalyzed allylic C-H sulfonylation of terminal alkenes have been developed. The former involves a direct Pd(II)-catalyzed oxidative C-H allylic sulfonylation in the presence of sulfinate anions, while the latter includes a sequential one-pot Pd(II)-catalyzed C-H allylic acetoxylation followed by a Pd(0)-catalyzed sulfonylation. The study examined the applicability of both protocols on 25 examples.
Two previously unknown protocols for Pd-catalyzed allylic C-H sulfonylation of terminal alkenes have been developed. While the former consists of a direct Pd(II)-catalyzed oxidative C-H allylic sulfonylation in the presence of sulfinate anions, the latter involves a sequential one-pot Pd(II)-catalyzed C-H allylic acetoxylation followed by a Pd(0)-catalyzed sulfonylation. The scope of both protocols was studied on 25 examples.
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