Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume 26, Issue 5, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.202200635
Keywords
Borates; High-pressure chemistry; Multianvil; Rare earths; Structure elucidation
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We describe the synthesis of a novel praseodymium molybdenum borate compound under high-pressure/high-temperature conditions. The compound, Pr3Mo4B6O24(OH)(3), exhibits monoclinic crystal system and presents a new structure type. The structure was determined through single-crystal structure determination and subsequently confirmed by powder X-ray diffraction, second harmonic generation measurement, single-crystal infrared, and Raman spectroscopic investigation.
We report on the synthesis of a new praseodymium molybdenum borate under high-pressure/high-temperature conditions. The new compound with the sum formula Pr3Mo4B6O24(OH)(3) crystallizes acentrically in the monoclinic space group Cm displaying a new structure type. The structure was solved via single-crystal structure determination. Additionally, the proposed structural model was confirmed by powder X-ray diffraction, second harmonic generation measurement, and single-crystal infrared and Raman spectroscopic investigation.
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