4.8 Article

Graphene-Skeleton Heat-Coordinated and Nanoamorphous-Surface-State Controlled Pseudo-Negative-Photoconductivity of Tiny SnO2 Nanoparticles

Journal

ADVANCED MATERIALS
Volume 27, Issue 23, Pages 3525-3532

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201500804

Keywords

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Funding

  1. National Basic Research Program of China [2011CB933300]
  2. National Natural Science Foundations of China [11204093, 11374110, 51371085, 11304106]
  3. Fundamental Research Funds for the Central Universities [HUST: 2014TS124]

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SnO2 nanoparticles display a pseudo-negative-photoconductivity (PsdNPC) effect, which shows that their resistance increases under light irradiation via a heating effect. The PsdNPC originates from intensive electron scattering of the nanoamorphous surface state of the SnO2 nanoparticles, resulting in a small inner current and a large absorption of moisture, leading to a large surface current. Graphene as the inner skeleton can shorten the response and recovery times.

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