4.8 Article

An Analysis of the Potential and Cost of the US Refinery Sector Decarbonization

Journal

ENVIRONMENTAL SCIENCE & TECHNOLOGY
Volume -, Issue -, Pages -

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.est.2c07440

Keywords

refinery decarbonization; renewable hydrogen; renewable energy; carbon capture; biocrude; cost of carbon avoidance; refinery cost per barrel crude

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This analysis explores decarbonization opportunities for U.S. refineries and the associated costs. By switching energy sources, implementing carbon capture and storage, and changing feedstock, refineries can reduce CO2 emissions. Only the third option can reduce emissions throughout the entire life cycle of refinery products. Combining all three strategies can achieve negative life-cycle CO2 emissions, with an average cost of $113-$477/MT CO2 or $54-$227/bbl of processed crude, driven by the expensive biocrude feedstock.
In 2019, U.S. petroleum refineries emitted 196 million metric tons (MT) of CO2, while the well-to-gate and the full life cycle CO2 emissions were significantly higher, reaching 419 and 2843 million MT of CO2, respectively. This analysis examines decarbonization opportunities for U.S. refineries and the cost to achieve both refinery level and complete life-cycle CO2 emission reductions. We used 2019 life-cycle CO2 emissions from U.S. refineries as a baseline and identified three categories of decarbonization opportunity: (1) switching refinery energy inputs from fossil to renewable sources (e.g., switch hydrogen source); (2) carbon capture and storage of CO2 from various refining units; and (3) changing the feedstock from petroleum crude to biocrude using various blending levels. While all three options can reduce CO2 emissions from refineries, only the third can reduce emissions throughout the life cycle of refinery products, including the combustion of fuels (e.g., gasoline and diesel) during end use applications. A decarbonization approach that combines strategies 1, 2, and 3 can achieve negative life-cycle CO2 emissions, with an average CO2 avoidance cost of $113-$477/MT CO2, or $54-$227/bbl of processed crude; these costs are driven primarily by the high cost of biocrude feedstock.

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