Characterizing the efficiency of low-cost LED lights for conducting laboratory studies to investigate polycyclic aromatic hydrocarbon photodegradation processes

Polycyclic aromatic hydrocarbons (PAHs) are common contaminants ubiquitously present in various waste products such as biosolids (e.g. wastewater sludges), oil spill residues (e.g. tarballs), road asphalts, and com-bustion byproducts. In this study, the photodegradation of PAHs is investigated under natural sunlight (cloudy and sunny/clear weather conditions), and using two types of artificial LED light sources. This is the first study to investigate the relative efficiency of low-cost LED light sources for conducting laboratory-scale PAH photo -degradation experiments and directly comparing the results against those obtained using natural sunlight. Two types of LED light sources are investigated in this study: a light source with a full-spectrum range (380 nm-780 nm) that can cover the broad wavelength range of solar light reaching the Earth's surface, and a light source with a UV-A range (365 nm) that covers the UV range of the solar spectrum reaching the Earth's surface. The results show that the degradation of high molecular weight (HMW) PAHs is primarily due to photodegradation, and other lighter PAHs are degraded by both photodegradation and evaporation processes. HMW PAH photo -degradation reactions follow the first-order degradation kinetics. The degradation rate constants of different PAHs are used to compare the relative efficiency of the light sources. The data show that the full-spectrum LED induced PAH photodegradation rates are similar to the natural sunlight induced rates. Furthermore, when the values of the rate constants are normalized to respective irradiance levels, the normalized rates for HMW PAH photodegradation under both full-spectrum LED light and natural sunlight are almost identical. However, the normalized photodegradation rate constants of HMW PAHs under the UV-A LED light are about two to three orders of magnitude higher than the sunlight as well as the full-spectrum-LED values. Therefore, the UV-A LED light is the optimal low-cost light source for studying PAH photodegradation processes under laboratory conditions.

Automated summary

This study investigates the photodegradation of PAHs under natural sunlight and two types of artificial LED light sources (full-spectrum and UV-A). The results show that high molecular weight PAHs are primarily degraded by photodegradation, while lighter PAHs are degraded by both photodegradation and evaporation. The rates of PAH photodegradation induced by full-spectrum LED light are similar to those induced by natural sunlight, but the rates under UV-A LED light are significantly higher. Therefore, UV-A LED light is the optimal low-cost light source for studying PAH photodegradation processes under laboratory conditions.