Novel synthesis of reed flower-like SmMnOx catalyst with enhanced low-temperature activity and SO2 resistance for NH3-SCR

In this work, a novel co-precipitation coupled solvothermal procedure is proposed to prepare a SmMnOx catalyst (SmMnOx-CP + ST) with a reed flower-like structure for the selective catalytic reduction of NOx by NH3 (NH3SCR). Over 90% NOx conversion and N2 selectivity was achieved at a low temperature range (25-200 degrees C), and 96% NOx conversion was achieved in the presence of 100 ppm SO2 at 75 degrees C. While the NH3-SCR of the SmMnOx catalysts prepared by co-precipitation (SmMnOx-CP) and solvothermal (SmMnOx-ST) methods performed much poorer than the SmMnOx-CP + ST catalyst. All catalysts were characterized by XRD, BET, SEM, XPS, H2-TPR, NH3-TPD, NOx-TPD, and FT-IR. The results revealed that the superior performance of the SmMnOx-CP + ST is due to the unique reed flower-like structure morphology, which endows the SmMnOx-CP + ST with the largest surface area, the strongest synergistic reaction of Sm and Mn, abundant surface oxygen species and surface active sites, and significantly enhances the redox ability. Furthermore, the amorphous reed flower-like structure showed strong short-range ordered interaction between the active components and weaken the formation of sulfates species. In addition, the highest content of Mn4+ and Mn3++Mn4+ greatly promotes the redox cycles of Sm2+ <-> Mn4+ and Sm2+ <-> Mn3+, and suppresses the production of sulfate species in the presence of SO2.

Automated summary

In this study, a novel co-precipitation coupled solvothermal procedure was used to prepare a SmMnOx catalyst with a reed flower-like structure, which exhibited excellent performance in the selective catalytic reduction of NOx by NH3 at low temperatures. The unique morphology of the catalyst, characterized by the largest surface area, strong synergistic reaction of Sm and Mn, abundant surface oxygen species and active sites, and enhanced redox ability, contributed to its superior catalytic performance. Moreover, the amorphous reed flower-like structure promoted short-range ordered interaction between active components and inhibited the formation of sulfate species.