Efficient degradation of sulfamethoxazole in various waters with peroxymonosulfate activated by magnetic-modified sludge biochar: Surface-bound radical mechanism

First time, this study synthesized a magnetic-modified sludge biochar (MSBC) as an activator of peroxymonosulfate (PMS) to eliminate sulfamethoxazole (SMX). The removal efficiency of SMX reached 96.1% at t = 60 min by PMS/MSBC system. The larger surface area and magnetic Fe3O4 of MSBC surface enhanced its activation performance for PMS. The PMS decomposition, premixing and reactive oxygen species (ROS) identification experiments combined with Raman spectra analysis demonstrated that the degradation process was dominated by surface-bound radicals. The transformed products (TPs) of SMX and the main degradation pathways were identified and proposed. The ecotoxicity of all TPs was lower than that of SMX. The magnetic performance was beneficial for its reuse and the removal efficiency of SMX was 83.3% even after five reuse cycles. Solution pH, HCO3- and CO32- were the critical environmental factors affecting the degradation process. MSBC exhibited environmental safety for its low heavy metal leaching. PMS/MSBC system also performed excellent removal performance for SMX in real waters including drinking water (88.1%), lake water (84.3%), Yangtze River water (83.0%) and sewage effluent (70.2%). This study developed an efficient PMS activator for SMX degradation in various waters and provided a workable way to reuse and recycle municipal sludge.

Automated summary

For the first time, researchers synthesized a magnetic-modified sludge biochar (MSBC) to activate peroxymonosulfate (PMS) and remove sulfamethoxazole (SMX). The PMS/MSBC system achieved a 96.1% removal efficiency of SMX within 60 minutes. The study identified the degradation process and proposed the main degradation pathways of SMX, as well as demonstrated the environmental safety and reuse potential of MSBC.