Analyses of polarisation effects and operando detection of lithium deposition in experimental half- and commercial full-cells

Article Chemistry, Physical

Combined dilatometry and voltage analysis for a reliable detection of lithium deposition on graphitic anodes

Leonard Jahn et al.

Summary: The study uncovers the impact of lithium deposition on cell voltage and thickness, demonstrating that dilation behavior and voltage analysis can be used to detect LD, proposing a Bayes algorithm for combined data detection.

JOURNAL OF POWER SOURCES (2022)

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Article Chemistry, Physical

Investigation of the distribution of relaxation times of a porous electrode using a physics-based impedance model

Yulong Zhao et al.

Summary: The analysis of the distribution of relaxation times (DRT) has gained wide attention in battery engineering due to its nondestructive nature and ability to differentiate electrochemical processes. A new theory is developed based on a deep understanding of the physics-based impedance model and the DRT method, providing a closed-form analytical expression for the DRT spectrum with clear physical meaning. It is also found that the relaxation time dispersion of EIS may have multiple origins.

JOURNAL OF POWER SOURCES (2022)

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Review Chemistry, Physical

Developing extreme fast charge battery protocols - A review spanning materials to systems

Eric J. Dufek et al.

Summary: Extreme fast charging (XFC) has become a focal research point in the lithium-battery community. Recent advances in charge protocols, including the use of advanced models and methods, have increased charge acceptance and decreased aging. These developments address material constraints and have the potential to significantly enhance the charging experience and lifespan of lithium batteries.

JOURNAL OF POWER SOURCES (2022)

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Article Electrochemistry

Modeling the inhomogeneous lithium plating in lithium-ion batteries induced by non-uniform temperature distribution

Tao Sun et al.

Summary: This study establishes a three-dimensional electrochemical model to analyze the inhomogeneous lithium plating behavior in large-format lithium-ion batteries. The results show that temperature gradients have a significant impact on the distribution of plated lithium and the battery voltage relaxation profile.

ELECTROCHIMICA ACTA (2022)

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Article Energy & Fuels

Lithium plating detection using differential charging current analysis in lithium-ion batteries

Markos Koseoglou et al.

Summary: The study introduces a novel method for detecting lithium plating in lithium-ion batteries by analyzing the charging current curve data during the constant-voltage charging process and utilizing the technique of differential current analysis (DCA) for detection. The effectiveness of the method has been experimentally validated and the correlation of the current plateau with lithium plating has been analyzed to enhance the understanding of the reversible lithium plating process during charging.

JOURNAL OF ENERGY STORAGE (2022)

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Article Energy & Fuels

Lithium plating detection using differential charging current analysis in lithium-ion batteries

Markos Koseoglou et al.

Summary: This paper presents a lithium plating detection method for lithium-ion batteries, which detects LP by examining a current plateau during the charging process and has been experimentally validated with established LP detection methods. The correlation of the current plateau with LP has been experimentally analyzed to enhance the sensitivity of LP detection methods.

JOURNAL OF ENERGY STORAGE (2022)

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Article Electrochemistry

In-operando Raman study of lithium plating on graphite electrodes of lithium ion batteries

M. A. Cabanero et al.

Summary: High spatial resolution in-operando Raman spectroscopy was used to study lithium deposition on graphite electrodes, showing that lithium is deposited and intercalated into graphite simultaneously. After 30 minutes, a second mechanism becomes dominant. The evolution of G and D bands of graphite and the lithium concentration in the electrolyte suggest that EC is slowly consumed after lithium plating begins.

ELECTROCHIMICA ACTA (2021)

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Article Chemistry, Physical

Detection of lithium plating in lithium-ion batteries by distribution of relaxation times

Xiang Chen et al.

Summary: The study proposes a non-destructive method for detecting lithium plating in batteries using distribution of relaxation times (DRT). By analyzing DRT results, the presence of lithium plating can be determined, which may help expand the application of battery safety warnings.

JOURNAL OF POWER SOURCES (2021)

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Article Chemistry, Physical

Analysis and detection of lithium deposition after fast charging of lithium-ion batteries by investigating the impedance relaxation

Felix Katzer et al.

Summary: The article introduces an in-situ detection method for detecting lithium deposition, which analyzes battery behavior for LD detection and adjusts charging rate based on detection results. Multiple methods are employed to detect LD, including coulombic efficiency, dilation method, differential voltage analysis, and impedance relaxation method. Characteristic frequencies are identified using impedance spectroscopy for mechanistic interpretation of the phenomena.

JOURNAL OF POWER SOURCES (2021)

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Article Multidisciplinary Sciences

Computation of distribution of relaxation times by Tikhonov regularization for Li ion batteries: usage of L-curve method

T. Paul et al.

Summary: In this paper, DRT functions are numerically calculated for different systems with impedance data, and the quality of impedance data is checked using Kramers-Kronig relations. The DRTs are calculated using Tikhonov regularization method and the physical significance of peaks are discussed through peak fitting program.

SCIENTIFIC REPORTS (2021)

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Article Chemistry, Physical

Operando video microscopy of Li plating and re-intercalation on graphite anodes during fast charging

Yuxin Chen et al.

Summary: This study used plan-view operando video microscopy to investigate lithium plating on graphite anodes in high-energy-density batteries. The results show that lithium plating mainly occurs on graphite particles and is correlated with local minimum of graphite electrode potential. Galvanic corrosion currents are responsible for lithium re-intercalation and dead lithium formation.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Electrochemistry

Detection of Lithium Plating in Li-Ion Cell Anodes Using Realistic Automotive Fast-Charge Profiles

Matteo Dotoli et al.

Summary: The widespread adoption of electric vehicles is hindered by range anxiety, but an optimized fast-charge profile can improve both charging time and battery life. Lithium plating is identified as a major factor affecting battery capacity fade.

BATTERIES-BASEL (2021)

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Article Electrochemistry

Determination of the Distribution of Relaxation Times by Means of Pulse Evaluation for Offline and Online Diagnosis of Lithium-Ion Batteries

Erik Goldammer et al.

Summary: The study presents a novel approach to derive the distribution of relaxation times (DRT) in lithium-ion batteries (LIBs) by evaluating relaxation voltage after a current pulse. This method improves the resolution of low-frequency impedance changes and identified degradation mechanisms, contributing to enhancing reliability and safety of LIBs. It was experimentally validated and found applicable in battery management systems.

BATTERIES-BASEL (2021)

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Article Chemistry, Physical

A new on-line method for lithium plating detection in lithium-ion batteries

Upender Rao Koleti et al.

JOURNAL OF POWER SOURCES (2020)

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Review Energy & Fuels

Electrochemical impedance spectroscopy study of commercial Li-ion phosphate batteries: A metrology perspective

Lisa Deleebeeck et al.

INTERNATIONAL JOURNAL OF ENERGY RESEARCH (2020)

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Article Chemistry, Physical

Detecting the Onset of Lithium Plating and Monitoring Fast Charging Performance with Voltage Relaxation

Zachary M. Konz et al.

ACS ENERGY LETTERS (2020)

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Article Electrochemistry

Investigating solid polymer and ceramic electrolytes for lithium-ion batteries by means of an extended Distribution of Relaxation Times analysis

Markus Hahn et al.

ELECTROCHIMICA ACTA (2020)

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Article Energy & Fuels

A Study on the Influence of Lithium Plating on Battery Degradation

Upender Rao Koleti et al.

ENERGIES (2020)

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Article Chemistry, Physical

Non-invasive investigation of predominant processes in the impedance spectra of high energy lithium-ion batteries with nickel-cobalt-aluminum cathodes

Pouyan Shafiei Sabet et al.

JOURNAL OF POWER SOURCES (2020)

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Review Electrochemistry

Review-Lithium Plating Detection Methods in Li-Ion Batteries

Umamaheswari Janakiraman et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2020)

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Article Chemistry, Physical

Separation of predominant processes in electrochemical impedance spectra of lithium-ion batteries with nickel-manganese-cobalt cathodes

Pouyan Shafiei Sabet et al.

JOURNAL OF POWER SOURCES (2019)

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Article Energy & Fuels

The development of optimal charging strategies for lithium-ion batteries to prevent the onset of lithium plating at low ambient temperatures

Upender Rao Koleti et al.

JOURNAL OF ENERGY STORAGE (2019)

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Article Electrochemistry

Optimized Process Parameters for a Reproducible Distribution of Relaxation Times Analysis of Electrochemical Systems

Markus Hahn et al.

BATTERIES-BASEL (2019)

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Article Electrochemistry

Generalized Distribution of Relaxation Times Analysis for the Characterization of Impedance Spectra

Michael A. Danzer

BATTERIES-BASEL (2019)

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Review Energy & Fuels

Lithium-ion battery fast charging: A review

Anna Tomaszewska et al.

ETRANSPORTATION (2019)

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Article Electrochemistry

How Observable Is Lithium Plating? Differential Voltage Analysis to Identify and Quantify Lithium Plating Following Fast Charging of Cold Lithium-Ion Batteries

Ian D. Campbell et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2019)

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Article Electrochemistry

Identification of Lithium Plating in Lithium-Ion Batteries using Nonlinear Frequency Response Analysis (NFRA)

Nina Harting et al.

ELECTROCHIMICA ACTA (2018)

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Review Chemistry, Physical

Li plating as unwanted side reaction in commercial Li-ion cells - A review

Thomas Waldmann et al.

JOURNAL OF POWER SOURCES (2018)

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Article Chemistry, Physical

Enabling fast charging - A battery technology gap assessment

Shabbir Ahmed et al.

JOURNAL OF POWER SOURCES (2017)

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Article Chemistry, Physical

Modeling of lithium plating induced aging of lithium-ion batteries: Transition from linear to nonlinear aging

Xiao-Guang Yang et al.

JOURNAL OF POWER SOURCES (2017)

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Article Electrochemistry

Nonlinear Frequency Response Analysis (NFRA) of Lithium-Ion Batteries

Nina Harting et al.

ELECTROCHIMICA ACTA (2017)

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Article Energy & Fuels

Multi-phase formation induced by kinetic limitations in graphite-based lithium-ion cells: Analyzing the effects on dilation and voltage response

Marius Bauer et al.

JOURNAL OF ENERGY STORAGE (2017)

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Article Electrochemistry

Effects of rest time after Li plating on safety behavior-ARC tests with commercial high-energy 18650 Li-ion cells

Thomas Waldmann et al.

ELECTROCHIMICA ACTA (2017)

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Article Chemistry, Physical

Voltage relaxation and impedance spectroscopy as in-operando methods for the detection of lithium plating on graphitic anodes in commercial lithium-ion cells

Stefan Schindler et al.

JOURNAL OF POWER SOURCES (2016)

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Article Electrochemistry

Optimization of Charging Strategy by Prevention of Lithium Deposition on Anodes in high-energy Lithium-ion Batteries - Electrochemical Experiments

Thomas Waldmann et al.

ELECTROCHIMICA ACTA (2015)

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Article Chemistry, Physical

Modeling graphite anodes with serial and transmission line models

J. Illig et al.

JOURNAL OF POWER SOURCES (2015)

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Article Chemistry, Physical

In situ detection of lithium metal plating on graphite in experimental cells

C. Uhlmann et al.

JOURNAL OF POWER SOURCES (2015)

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Article Electrochemistry

A Method for Improving the Robustness of linear Kramers-Kronig Validity Tests

M. Schoenleber et al.

ELECTROCHIMICA ACTA (2014)

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Article Chemistry, Physical

Nondestructive detection, characterization, and quantification of lithium plating in commercial lithium-ion batteries

Mathias Petzl et al.

JOURNAL OF POWER SOURCES (2014)

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Article Chemistry, Physical

Physical characterization of the charging process of a Li-ion battery and prediction of Li plating by electrochemical modelling

N. Legrand et al.

JOURNAL OF POWER SOURCES (2014)

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Review Chemistry, Physical

A review of lithium deposition in lithium-ion and lithium metal secondary batteries

Zhe Li et al.

JOURNAL OF POWER SOURCES (2014)

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Article Chemistry, Physical

Effects of current densities on the lithium plating morphology at a lithium phosphorus oxynitride glass electrolyte/copper thin film interface

Fumihiro Sagane et al.

JOURNAL OF POWER SOURCES (2013)

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Article Chemistry, Physical

Understanding the impedance spectrum of 18650 LiFePO4-cells

J. Illig et al.

JOURNAL OF POWER SOURCES (2013)

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Article Electrochemistry

Overcharge Effect on Morphology and Structure of Carbon Electrodes for Lithium-Ion Batteries

Wenquan Lu et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2012)

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Article Chemistry, Physical

Studies on LiFePO4 as cathode material using impedance spectroscopy

Jan Philipp Schmidt et al.

JOURNAL OF POWER SOURCES (2011)

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Article Chemistry, Physical

Fundamentals of battery dynamics

A Jossen

JOURNAL OF POWER SOURCES (2006)

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Article Electrochemistry

Studies on charging lithium-ion cells at low temperatures

J Fan et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2006)

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Analyses of polarisation effects and operando detection of lithium deposition in experimental half- and commercial full-cells

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