Carbazole-s-sulfobenzimide derivative exhibiting mechanochromic thermally activated delayed fluorescence as emitter for flexible OLEDs: Theoretical and experimental insights

For the first time exploiting sulfobenzimide moiety as an acceptor unit, the new type of donor-sigma-acceptor emitter exhibiting thermally activated delayed fluorescence (TADF) is demonstrated. In different solutions, the synthesized compound emits light resulting from either locally excited carbazole moiety or trough-space charge transfer (exciplex-like) between carbazole and sulfobenzimide units. In the solid state, this emitter demonstrates aggregation-induced emission enhancement and different emission colours due to its different conformations. The mechanoluminescence of the donor-sigma-acceptor compound was observed and studied in detail by experimental and theoretical approaches including single-crystal and powder X-ray analyses. Electroluminescence of the different colours was observed when the compound was utilized as non-doped TADF emitter in rigid and flexible organic light-emitting diodes fabricated on glass or poly(ethylene terephthalate) substrates. The device fabricated on the rigid substrate exhibited the best performance with maximum current efficiency, power efficiency, and external quantum efficiency of 11.0 cd A(-1), 3.0 lm W-1, and 4.3%, respectively.

Automated summary

In this study, a new type of donor-sigma-acceptor emitter that exhibits thermally activated delayed fluorescence (TADF) is demonstrated for the first time, with sulfobenzimide moiety used as an acceptor unit. The emission of the synthesized compound in different solutions can be attributed to either locally excited carbazole moiety or trough-space charge transfer (exciplex-like) between carbazole and sulfobenzimide units. In the solid state, aggregation-induced emission enhancement and different emission colors are observed due to different conformations. The mechanoluminescence and electroluminescence properties of the compound are extensively studied, and the compound shows good performance as a non-doped TADF emitter in organic light-emitting diodes fabricated on different substrates.