4.6 Article

Green facile synthesis of biowaste-converted Cu-Cu2O/BPC for non-enzymatic hydrogen peroxide sensing

Journal

DIAMOND AND RELATED MATERIALS
Volume 130, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.diamond.2022.109458

Keywords

Porous carbon; Biowaste; Cu-based; Non-enzymatic; Sensing

Funding

  1. Open Research Fund of Key laboratory of Processing and Quality Evaluation Technology of Green Plastics of China National Light Industry Council [PQETGP2021004]
  2. Key Project of the Chinese Ministry of Education [213024A]
  3. National Natural Science Foundation of China [51601133, 51574182, 51401150]
  4. Graduate Education Innovation Fund Project of Wuhan Institute of Technology [CX2021354]

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Despite the rapid development of non-enzyme sensors, there is an urgent need for a sensor that can produce sensing materials without the use of reducing agents. In this study, a green biowaste conversion strategy was developed to fabricate advanced Cu-based sensing material, which showed excellent catalytic activity and sensing performance.
Despite the rapid development of non-enzyme sensors, there is an urgent need for a sensor that can produce sensing materials without the use of reducing agents. Herein,a green biowaste conversion strategy is elabo-rately developed to fabricate advanced Cu-based sensing material, in which the Cu-Cu2O/BPC-1 was obtained by facilely carbonizing the bamboo powder soaked with Cu (NO3)2 without using any reduction agents. Particularly, the Cu-Cu2O particles were uniformly anchored on the mesoporous carbon plate. Profited from the synergistic effect between biomass carbon plate and Cu-Cu2O particles, electrochemical measurements showed that the prepared Cu-Cu2O/BPC-Y/GCE sensor demonstrated prominent catalytic activity for H2O2. In particular, the Cu-Cu2O/BPC-1/GCE sensor displayed a wide linear range (1-8330 mu M), a low detection limit(0.35 mu M) (S/N = 3), and excellent selectivity, reproducibility and stability. This work provides a cost-effective and environmentally friendly strategy to fabricate the non-enzymatic H2O2 sensor.

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