Improving the synthetic H2 production catalyst design strategy with the neurotransmitter dopamine

The strategic incorporation of the neurotransmitter dopamine around a cobaloxime core resulted in excellent electrocatalytic (rate 8400 s(-1)) and photocatalytic H-2 production under neutral aqueous conditions. The influence of the synthetic outer coordination sphere features continues even with a phenylene-diimino-dioxime motif-coordinated cobalt core.

Automated summary

The strategic incorporation of dopamine, a neurotransmitter, around a cobaloxime core enabled excellent electrocatalytic (rate 8400 s(-1)) and photocatalytic H-2 production under neutral aqueous conditions. The influence of the synthetic outer coordination sphere features persists even with a phenylene-diimino-dioxime motif-coordinated cobalt core.