4.7 Article

Towards hydrogen-rich ionic (NH4)(BH3NH2BH2NH2BH3) and related molecular NH3BH2NH2BH2NH2BH3

Journal

DALTON TRANSACTIONS
Volume 52, Issue 12, Pages 3586-3595

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2dt03674f

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Attempts to synthesize the ionic compound (NH4)(BH3NH2BH2NH2BH3) via a metathetical approach resulted in a mixture of the target compound and a partially dehydrogenated molecular NH3BH2NH2BH2NH2BH3 product. Characterization of the mixed specimen was performed using NMR and vibrational spectroscopies, and the cocrystal structure was analyzed using powder X-ray diffraction data and density functional theory calculations. Despite their high hydrogen content, similar to ammonia borane, both compounds released hydrogen contaminated with borazine, as well as traces of ammonia and diborane.
Attempts of the synthesis of ionic (NH4)(BH3NH2BH2NH2BH3) via a metathetical approach resulted in a mixture of the target compound and partly dehydrogenated molecular NH3BH2NH2BH2NH2BH3 product. The mixed specimen was characterised by NMR and vibrational spectroscopies, and the cocrystal structure was analyzed from powder X-ray diffraction data supported by theoretical density functional theory calculations. The compound crystallises in a P2(1)/c unit cell with the lattice parameters of a = 13.401(11) angstrom, b = 13.196(8) angstrom, c = 17.828(12) angstrom, beta = 128.83(4)degrees, V = 2556(3) angstrom(3) and Z = 16. Despite their impressive hydrogen content, similar to ammonia borane, both title compounds release hydrogen substantially polluted with borazine and traces of ammonia and diborane.

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