4.7 Article

Probing borafluorene B-C bond insertion with gold acetylide and azide

Journal

DALTON TRANSACTIONS
Volume 52, Issue 3, Pages 668-674

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2dt03672j

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The reaction of Ph3PAuN3 with 9-Ph-9-borafluorene resulted in the complexation of azide to boron, while a gold acetylide reacted with 9-Ph-9-borafluorene to insert the acetylide carbon and form a six-membered boracycle with an exocyclic double bond.
The reaction of Ph3PAuN3 with 9-Ph-9-borafluorene resulted in complexation of the azide to boron while a gold acetylide reacted with 9-Ph-9-borafluorene to insert the acetylide carbon to access a six-membered boracycle with an exocyclic double bond.

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