Water stable MOFs as emerging class of porous materials for potential environmental applications

Metal-organic frameworks (MOFs) are extensively recognized for their wide applications in a variety of fields such as water purification, adsorption, sensing, catalysis and drug delivery. The fundamental characteristics of the majority of MOFs, such as their structure and shape, are known to be sensitively impacted by water or moisture. As a result, a thorough evaluation of the stability of MOFs in respect to factors linked to these property changes is required. It is quite rare for MOFs in their early stages to have strong water-stability, which is necessary for the commercialization and development of wider applications of this interesting material. Also, numerous applications in presence of water have progressed considerably as a proof of concept stage in the past and a growing number of water-stable MOFs (WSMOFs) have been discovered in recent years. This review discusses the variables and processes that affect the aqueous stability of several MOFs, including imidazolate and carboxylate frameworks. Accordingly, this article will assist researchers in accurately evaluating how water affects the stability of MOFs so that effective techniques can be identified for the advancement of water-stable metal-organic frameworks (WSMOFs) and for their effective applications toward a variety of fields.

Automated summary

Metal-organic frameworks (MOFs) have wide applications in various fields, and their stability is sensitive to water or moisture. Strong water-stability is rare in early-stage MOFs, but more water-stable MOFs (WSMOFs) have been discovered in recent years. This review discusses the variables and processes affecting the aqueous stability of different MOFs, and aims to assist researchers in accurately evaluating the impact of water on MOF stability and identifying effective techniques for the development of WSMOFs and their applications.