Synthesis, characterization and adsorption behavior of modified cellulose nanocrystals towards different cationic dyes

Green and efficient removal of polluted materials are essential for the sustainability of a clean and green envi-ronment. Nanomaterials, particularly cellulose nanocrystals (CNCs), are abundant in nature and can be extracted from various sources, including cotton, rice, wheat, and plants. CNCs are renewable biomass materials with a high concentration of polar functional groups. This study used succinic anhydride to modify the surface of native cellulose nanocrystals (NCNCs). Succinic anhydride has been frequently used in adhesives and sealant chemicals for a long time, and here, it is evaluated for dye removal performance. The morphology and modification of CNCs studied using FTIR, TGA & DTG, XRD, SEM, AFM, and TEM. The ability of modified cellulose nanocrystals (MCNCs) to adsorb cationic golden yellow dye and methylene blue dye was investigated. The MCNCs exhibited high adsorption affinity for the two different cationic dyes. The maximum adsorption efficiency of NCNCs and MCNCs towards the cationic dye was 0.009 and 0.156 wt%. The investigation for adhesive properties is based on the strength and toughness of MCNCs. MCNCs demonstrated improved tensile strength (2350 MPa) and modulus (13.9 MPa) using E-51 epoxy system and a curing agent compared to 3 wt% composites. This research lays the groundwork for environmentally friendly fabrication and consumption in the industrial sector.

Automated summary

Green and efficient removal of polluted materials is crucial for maintaining a clean and sustainable environment. This study explores the modification of cellulose nanocrystals (CNCs) using succinic anhydride and demonstrates the high adsorption affinity of the modified CNCs (MCNCs) towards cationic dyes. Additionally, MCNCs exhibit improved adhesive properties, laying the foundation for environmentally friendly fabrication and consumption.