Di-Iron(II) [2+2] Helicates of Bis-(Dipyrazolylpyridine) Ligands: The Influence of the Ligand Linker Group on Spin State Properties

Article Chemistry, Multidisciplinary

Unravelling of a [High Spin-Low Spin] ⇆ [Low Spin-High Spin] Equilibrium in Spin-Crossover Iron(II) Dinuclear Helicates Using Paramagnetic NMR Spectroscopy

Dmitry Yu Aleshin et al.

Summary: The study successfully observed the dynamics of two rare spin states, opening up new possibilities for information storage and processing.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

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Article Chemistry, Multidisciplinary

Structural Insights into Hysteretic Spin-Crossover in a Set of Iron(II)-2,6-bis(1H-Pyrazol-1-yl)Pyridine) Complexes

Nithin Suryadevara et al.

Summary: This study investigates the structural facets of bistable spin-crossover complexes and their role in inducing hysteresis. Through single-crystal X-ray diffraction studies, it is found that molecular reorganizations and conformation switching contribute to the observed spin-state switching and hysteresis. These insights could potentially aid in the design of molecule-based switching and memory elements.

CHEMISTRY-A EUROPEAN JOURNAL (2022)

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Article Chemistry, Multidisciplinary

Iron(II) Complexes of 4-(Alkyldisulfanyl)-2,6-di(pyrazolyl)pyridine Derivatives. Correlation of Spin-Crossover Cooperativity with Molecular Structure Following Single-Crystal-to-Single-Crystal Desolvation

Rafal Kulmaczewski et al.

Summary: This study investigates the solvated crystals of complex salts [Fe(L-1)(2)]X-2 (1X(2)) formed from common organic solvents and characterizes their crystal structure and spin-crossover properties.

CRYSTAL GROWTH & DESIGN (2022)

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Article Chemistry, Inorganic & Nuclear

Thermal and photoinduced spin-crossover of mononuclear FeII complexes based on bppCHO ligand

Qianqian Yang et al.

Summary: The study of two iron(o) complexes reveals that the spin states and spin-crossover behavior are influenced by supramolecular interactions and crystal packing effects. Complex 1·ClO4 shows light-induced excited spin state trapping and two-step spin-crossover at room temperature, while complex 1·BF4 exhibits gradual spin-crossover behavior. Magnetostructural analysis provides insight into the differences in the spin-crossover properties of the two complexes.

DALTON TRANSACTIONS (2022)

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Article Chemistry, Inorganic & Nuclear

Heteroleptic iron(ii) complexes of chiral 2,6-bis(oxazolin-2-yl)-pyridine (PyBox) and 2,6-bis(thiazolin-2-yl)pyridine ligands - the interplay of two different ligands on the metal ion spin sate

Namrah Shahid et al.

Summary: This study successfully synthesized a series of nitrite complex compounds with oxygen heterocyclic and thiazole groups as ligands by adjusting their acid-base properties and steric hindrance. It was found that these compounds exhibit gradual spin-crossover behavior in both solution and solid state.

DALTON TRANSACTIONS (2022)

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Article Chemistry, Multidisciplinary

Co-crystallisation as a modular approach to the discovery of spin-crossover materials

Lee T. Birchall et al.

Summary: In this study, co-crystallisation is proposed as a strategy for materials discovery in the field of switchable spin crossover (SCO) systems. By synthesising 11 new cocrystals using different dipyridyl coformers, the authors demonstrate that the supramolecular architecture and spin crossover behavior of the cocrystals can be modified through changing the coformer. This presents a rapid, facile, and highly modular tool for the discovery of new switchable materials, and has the potential for wider applicability in the design of hybrid multifunctional materials.

CHEMICAL SCIENCE (2022)

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Article Chemistry, Inorganic & Nuclear

Tuning the Spin-Crossover Behaviour in Fe(II) Polymeric Composites for Food Packaging Applications

Zoi G. Lada et al.

Summary: This study aims to explore the technological potential of spin-crossover (SCO) complexes incorporated into polymers and investigate the interaction between polymer and SCO complex that could affect the SCO behavior. The results show that the structural properties of the polymer matrix and SCO complex can significantly influence the performance and behavior of the composite materials.

MAGNETOCHEMISTRY (2022)

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Article Chemistry, Multidisciplinary

A spin crossover FeII4L6 cage based on pyridyl-hydrazone sites

Weiyang Li et al.

Summary: A Fe-II based supramolecular cage with pyridyl-hydrazone ligand scaffolds displaying temperature induced spin crossover behavior was reported, and density functional theory calculations were used to investigate the cause of this phenomenon based on the ligand structure. The results suggest that low-spin cages with pyridyl-imine sites could potentially undergo spin crossover when carefully manipulating the functional groups in the ligand system.

CHEMICAL COMMUNICATIONS (2022)

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Article Materials Science, Multidisciplinary

Supramolecular FeII4L4 cage for fast ammonia sensing

Weiyang Li et al.

Summary: The design and construction of colorimetric ammonia (NH3) sensors with high selectivity, great stability, and short response times at room temperature are crucial for human health and food safety. This study presents a chiral supramolecular FeII4L4 metal-organic cage (MOC-1) that can detect NH3(g) in under 10 seconds at room temperature and was used to monitor food safety on fresh bacon bits at 4 degrees C. The MOC-1 sensor demonstrated superior selectivity among NH3(g) and twelve other analytes, and the sensing mechanism is associated with a high-spin to low-spin transition of the Fe-II ions.

JOURNAL OF MATERIALS CHEMISTRY C (2022)

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Article Chemistry, Multidisciplinary

A ferric guest inside a spin crossover ferrous helicate

Leoni A. Barrios et al.

Summary: This article presents a designed dimetallic Fe(ii) helicate made with biphenylene-bridged bispyrazolylpyridine ligands, which exhibits spin crossover at temperatures higher than ambient. It is also demonstrated that this helicate has the ability to encapsulate an S = 5/2 tris-oxalato Fe(iii) ion, leading to a significant reduction in the spin relaxation dynamics of the encapsulated guest.

CHEMICAL COMMUNICATIONS (2022)

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Review Chemistry, Multidisciplinary

Sublimable Spin-Crossover Complexes: From Spin-State Switching to Molecular Devices

Kuppusamy Senthil Kumar et al.

Summary: This review covers the advances in vacuum-sublimable SCO complexes, including the design and synthesis of functional SCO complexes, on-surface SCO of thin films, and various device architectures based on sublimable SCO complexes.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Multiscale Approach of Spin Crossover Materials: A Concept Mixing Russian Dolls and Domino Effects

Philippe Guionneau et al.

Summary: The concept of multiscale understanding of SCO emphasizes the importance of considering structure-property relationships at different physical scales to fully grasp and take advantage of the phenomenon. This approach expands the range of potential applications, including the development of shape memory materials.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

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Article Chemistry, Multidisciplinary

A Reversible Hydrogen-Bond Isomerization Triggered by an Abrupt Spin Crossover near Room Temperature

Veronica Jornet-Molla et al.

Summary: The spin crossover salt [Fe(bpp)(2)](isonicNO)(2). 2.4 H2O undergoes a very abrupt spin crossover at 274.4 K, with reversible response to light irradiation or temperature change; Isotopic effects in the thermomagnetic behavior highlight the significance of hydrogen bonds in determining the magnetic state; The compound can be reversibly dehydrated to produce 1, which also exhibits spin crossover coupled with H-bond isomerization, resulting in strong kinetic effects in the thermomagnetic properties.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

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Article Chemistry, Multidisciplinary

Structural Transformations and Spin-Crossover in [FeL2]2+ Salts (L=4-{tert-Butylsulfanyl}-2,6-di{pyrazol-1-yl}pyridine): The Influence of Bulky Ligand Substituents

Rafal Kulmaczewski et al.

Summary: The study investigates the behavior of various iron complexes in solvent loss and thermal spin-crossover, revealing the complexity of photoinduced transitions and the diverse spin behaviors observed. The crystallographic characterization highlights the complexity of the system and the different observed spin behaviors during the transformations.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

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Article Chemistry, Multidisciplinary

Abundant Solvatomorphism-Tuned Spin Crossover in a Dinuclear Fe(II) Compound: Computational Insights on Molecular Distortion and Packing Effects

Feng-Lei Yang et al.

Summary: A series of solvates based on a dinuclear Fe(II) complex were synthesized and showed abundant variations in spin crossover properties, emphasizing the critical role of the crystal lattice contributions. Computational studies on these solvatomorphs revealed varying spin state behaviors due to different crystal lattice effects and molecular distortions, providing insights for designing compounds with selected properties.

CRYSTAL GROWTH & DESIGN (2021)

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Review Chemistry, Multidisciplinary

Spin-Crossover Molecules on Surfaces: From Isolated Molecules to Ultrathin Films

Lalminthang Kipgen et al.

Summary: This article summarizes the research on spin-crossover molecules on solid surfaces in molecular spintronics, covering a range from single molecules to ultrathin films, mainly in the sub-10 nm range. The achievements, challenges, and prospects in this field are highlighted.

ADVANCED MATERIALS (2021)

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Review Chemistry, Inorganic & Nuclear

Spin crossover and valence tautomerism conductors

Min Wang et al.

Summary: Research on multifunctional molecular materials with both magnetic bistability and electrical conductivity has expanded in the last two decades, providing materials with practical application prospects. This review presents recent progress on spin crossover and valence tautomerism conductors, focusing on syntheses, strategies, crystal structures, magnetic properties, and conductivities of such materials, as well as the synergistic and cooperative properties of bistability and conductivity.

COORDINATION CHEMISTRY REVIEWS (2021)

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Article Chemistry, Inorganic & Nuclear

Reversible Photo- and Thermo-Induced Spin-State Switching in a Heterometallic {5d-3d} W2Fe2 Molecular Square Complex

Krishna Kaushik et al.

Summary: By utilizing the complex-as-a-ligand strategy, a cyanide-bridged [W2Fe2] molecular square complex has been successfully self-assembled, demonstrating thermo-induced spin crossover and photoinduced spin-state switching effects.

INORGANIC CHEMISTRY (2021)

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Article Chemistry, Inorganic & Nuclear

Supramolecular Modulation of Spin Crossover in an Fe(II) Dinuclear Triple Helicate

Alexander R. Craze et al.

Summary: This study investigates the interaction between crystal packing, intermolecular interactions, and the magnetic behavior of SCO materials. The research found that a more separated array of SCO units leads to more extensive spin-transitions, while a tightly arranged lattice environment stabilizes the low-spin state.

INORGANIC CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Room-Temperature Spin Crossover in a Solution of Iron(II) Complexes with N,N′-Disubstituted Bis(pyrazol-3-yl)pyridines

Dmitry Yu Aleshin et al.

Summary: In this study, the effects of two chemical modifications and different solvents on the spin-crossover behavior in high-spin iron(II) complexes were investigated using solution NMR spectroscopy. The research revealed that with the recent design of substituents, the first iron(II) complex of N,N'-disubstituted 3-bpp can undergo almost complete spin-crossover in a less polar solvent.

ACS OMEGA (2021)

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Article Chemistry, Multidisciplinary

A Family of Heterobimetallic Cubes Shows Spin-Crossover Behaviour Near Room Temperature

Matthias Hardy et al.

Summary: The study utilized 4-(4 '-pyridyl)aniline as an organic building block in combination with three different aldehyde components and metal(II) salts to synthesize three different Fe8Pt6-cubes and their corresponding Zn8Pt6 analogues through the subcomponent self-assembly approach. The structures obtained using iron(II) salts exhibited spin-crossover behavior in solution, while the ones obtained using zinc(II) salts were diamagnetic. The spin-transition temperature T-1/2 was found to vary depending on the aldehyde component used, providing a construction kit for the deliberate synthesis of spin-crossover compounds with tailored transition properties.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Chiral Resolution of Spin-Crossover Active Iron(II) [2x2] Grid Complexes

Nithin Suryadevara et al.

Summary: Enantiomerically pure Fe(II) grid complexes were successfully prepared by designing novel chiral ligands, allowing for the fabrication of magneto-chiral molecular devices. The chiral resolution of these complexes enables controlled programmable separation before synthesis. The experimental and calculated CD spectra showed good agreement, confirming the enantiomeric purity of the complexes.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

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Article Chemistry, Inorganic & Nuclear

Structures and Spin States of Iron(II) Complexes of Isomeric 2,6-Di(1,2,3-triazolyl)pyridine Ligands

Izar Capel Berdiell et al.

Summary: The study investigates the stability and spin states of iron(II) complex salts with different ligands through experimental and computational methods. It is found that the iron(II) complex salts exhibit different spin states under the influence of different ligands, which are related to the coordination mode and basicity of the ligands.

INORGANIC CHEMISTRY (2021)

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Article Chemistry, Inorganic & Nuclear

Spin-States of Diastereomeric Iron(II) Complexes of 2,6-Bis(thiazolin-2-yl)pyridine (ThioPyBox) Ligands and a Comparison with the Corresponding PyBox Derivatives

Namrah Shahid et al.

Summary: This study investigates the structural differences between iron complexes with different thiazolinyl chiral ligands, showing that larger and more flexible thiazolinyl rings can reduce steric hindrances. Additionally, the influence of larger heterocyclic S atoms on steric hindrances is more significant. Under certain conditions, ligand redistribution does not result in racemization of homochiral and heterochiral complexes.

INORGANIC CHEMISTRY (2021)

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Article Chemistry, Inorganic & Nuclear

An azido-bridged [Fe4II] grid-like molecule showing spin crossover behaviour

Zhilin Guo et al.

Summary: The study successfully obtained two Fe(ii) grid-like complexes using a coordination-driven supramolecular assembly strategy, demonstrating spin-crossover behavior in azido-bridged complexes. By substitution of the ligand, the complex showed a synergistic effect between spin-crossover behavior and luminescence.

DALTON TRANSACTIONS (2021)

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Article Chemistry, Multidisciplinary

A ring of grids: a giant spin-crossover cluster

Takuya Shiga et al.

Summary: The two iron complexes differ in structure and composition, with 1 having a bis-chelate structure with two protonated ligands, while 2 has a ring-shape structure comprising four [2 x 2] grid moieties and four mononuclear units.

CHEMICAL COMMUNICATIONS (2021)

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Article Chemistry, Inorganic & Nuclear

Exceptionally high temperature spin crossover in amide-functionalised 2,6-bis(pyrazol-1-yl)pyridine iron(II) complex revealed by variable temperature Raman spectroscopy and single crystal X-ray diffraction

Max Attwood et al.

Summary: The synthesis and characterization of a novel amide-functionalised ligand and its iron complex salts indicate a spin-crossover phenomenon, with differences in crystal structures between low and high spin states attributed to inter-molecular hydrogen bonding.

DALTON TRANSACTIONS (2021)

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Article Chemistry, Multidisciplinary

The number and shape of lattice solvent molecules controls spin-crossover in an isomorphous series of crystalline solvate salts

Izar Capel Berdiell et al.

Summary: The study investigated the structure and spin-transition behavior of compounds containing the [FeL2] group at low temperatures. When the ligand solvent is MeCN, the material's spin transition exhibits a hysteretic phenomenon, while in EtCN solvent the spin transition occurs in a two-step process.

CHEMICAL COMMUNICATIONS (2021)

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Article Chemistry, Inorganic & Nuclear

Switching on thermal and light-induced spin crossover by desolvation of [Fe(3-bpp)2](XO4)2•solvent (X = Cl, Re) compounds

Abdelhak Djemel et al.

Summary: Thermal desolvation is an attractive method for post-synthetic modification of switchable materials. Two new compounds were synthesized and characterized, showing different spin conversion behaviors in solvated and desolvated states through spectroscopic, magnetic, and photomagnetic studies.

INORGANIC CHEMISTRY FRONTIERS (2021)

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Review Chemistry, Multidisciplinary

Controlling dynamic magnetic properties of coordination clusters via switchable electronic configuration

Wei Huang et al.

Summary: Large-sized coordination clusters, as a new class of molecular materials, display dynamic magnetic properties through the synergy of multiple components. Understanding the nature of dynamic magnetism at an atomic level is crucial for realizing desired properties.

CHEMICAL SOCIETY REVIEWS (2021)

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Article Chemistry, Inorganic & Nuclear

Influence of ligand substituent conformation on the spin state of an iron(ii)/di(pyrazol-1-yl)pyridine complex

Rafal Kulmaczewski et al.

Summary: The temperature of the solution-phase spin-crossover equilibrium in iron(ii) complexes of 4-alkylsulfanyl-2,6-di{pyrazol-1-yl}pyridine (bpp(SR)) complexes is strongly dependent on the alkylsulfanyl substituent, which is determined by the conformation of the alkylsulfanyl groups in the complexes.

DALTON TRANSACTIONS (2021)

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Article Chemistry, Multidisciplinary

The flexibility of long chain substituents influences spin-crossover in isomorphous lipid bilayer crystals†‡

Iurii Galadzhun et al.

Summary: The Fe(II) complexes exhibit high-spin states at room temperature, but only one of the compounds undergoes a stepwise spin transition upon cooling, potentially due to the different conformational flexibilities of their long chain substituents.

CHEMICAL COMMUNICATIONS (2021)

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Article Chemistry, Multidisciplinary

Interplay between spin crossover and proton migration along short strong hydrogen bonds

Veronica Jornet-Molla et al.

Summary: This study found that iron(ii) salt compound exhibits different spin states at different temperatures, and the light-induced excited state affects proton motion, demonstrating complex and diverse interactions.

CHEMICAL SCIENCE (2021)

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Review Nanoscience & Nanotechnology

Molecular magnetism: from chemical design to spin control in molecules, materials and devices

Eugenio Coronado

NATURE REVIEWS MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Towards the Molecular Design of Spin-Crossover Complexes of 2,6-Bis(pyrazol-3-yl)pyridines

Igor Nikovskiy et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

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Article Chemistry, Inorganic & Nuclear

A Rare Example of a Complete, Incomplete, and Non-Occurring Spin Transition in a [Fe2L3]X4 Series Driven by a Combination of Solvent and Halide-Anion-Mediated Steric Factors

Alexander R. Craze et al.

INORGANIC CHEMISTRY (2020)

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Article Chemistry, Inorganic & Nuclear

Monitoring Fe(II) Spin-State Equilibria via Eu(III) Luminescence in Molecular Complexes: Dream or Reality?

Timothee Lathion et al.

INORGANIC CHEMISTRY (2020)

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Article Chemistry, Inorganic & Nuclear

Phase Trapping in Multistep Spin Crossover Compound

Fabian Fuermeyer et al.

INORGANIC CHEMISTRY (2020)

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Article Chemistry, Inorganic & Nuclear

Synthesis and magnetic properties of tetrahedral tetranuclear iron(II) complexes with bis(bidentate)-type Schiff bases containing imidazole groups

Tsubasa Tanaka et al.

INORGANICA CHIMICA ACTA (2020)

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Article Physics, Condensed Matter

Theoretical analysis of pressure induced spin crossover phenomenon in a di-nuclear Fe(II) molecular complex

Atasi Chakraborty et al.

JOURNAL OF PHYSICS-CONDENSED MATTER (2020)

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Article Chemistry, Multidisciplinary

Heat Capacity and Thermal Damping Properties of Spin-Crossover Molecules: A New Look at an Old Topic

Karl Ridier et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Multidisciplinary

A Mixed-Valence {Fe13} Cluster Exhibiting Metal-to-Metal Charge-Transfer-Switched Spin Crossover

Wen Wen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

X-Seed 4: updates to a program for small-molecule supramolecular crystallography

Leonard J. Barbour

JOURNAL OF APPLIED CRYSTALLOGRAPHY (2020)

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Review Chemistry, Inorganic & Nuclear

Spin crossover polymer composites, polymers and related soft materials

Alejandro Enriquez-Cabrera et al.

COORDINATION CHEMISTRY REVIEWS (2020)

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Article Chemistry, Inorganic & Nuclear

Allosteric Spin Crossover Induced by Ligand-Based Molecular Alloying

Carlos Bartual-Murgui et al.

INORGANIC CHEMISTRY (2020)

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Article Chemistry, Inorganic & Nuclear

Bistable spin-crossover in a new series of [Fe(BPP-R)2]2+ (BPP=2,6-bis(pyrazol-1-yl)pyridine; R = CN) complexes

Kuppusamy Senthil Kumar et al.

DALTON TRANSACTIONS (2020)

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Article Chemistry, Multidisciplinary

Thermo- and electro-switchable Cs⊂{Fe4-Fe4} cubic cage: spin-transition and electrochromism

Jana Glatz et al.

CHEMICAL COMMUNICATIONS (2020)

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Article Materials Science, Multidisciplinary

4D printing with spin-crossover polymer composites

Mario Piedrahita-Bello et al.

JOURNAL OF MATERIALS CHEMISTRY C (2020)

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Article Chemistry, Inorganic & Nuclear

Supramolecular assemblies based on Fe8L12 cubic metal-organic cages: synergistic adsorption and spin-crossover properties

Hui-Shu Lu et al.

DALTON TRANSACTIONS (2020)

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Review Chemistry, Multidisciplinary

Bistable molecular materials with dynamic structures

Zi-Shuo Yao et al.

CHEMICAL COMMUNICATIONS (2020)

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Article Chemistry, Multidisciplinary

Structure Switching and Modulation of the Magnetic Properties in Diarylethene-Bridged Metallosupramolecular Compounds by Controlled Coordination-Driven Self-Assembly

Zhao-Yang Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Inorganic & Nuclear

Polynuclear Iron(11) Complexes with 2,6-Bis(pyrazol-1-yl)pyridine-anthracene Ligands Exhibiting Highly Distorted High-Spin Centers

Ivan Salitros et al.

INORGANIC CHEMISTRY (2019)

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Article Chemistry, Multidisciplinary

Giant Barocaloric Effect at the Spin Crossover Transition of a Molecular Crystal

Steven P. Vallone et al.

ADVANCED MATERIALS (2019)

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Article Chemistry, Inorganic & Nuclear

Relationship between the Molecular Structure and Switching Temperature in a Library of Spin-Crossover Molecular Materials

Malcolm A. Halcrow et al.

INORGANIC CHEMISTRY (2019)

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Article Chemistry, Multidisciplinary

Slow Dynamics of the Spin-Crossover Process in an Apparent High-Spin Mononuclear FeII Complex

Yi Shan Ye et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Inorganic & Nuclear

Symmetry Breaking and Two-Step Spin-Crossover Behavior in Two Cyano-Bridged Mixed-Valence {FeIII2(μ-CN)4FeII2} Clusters

Chunyang Zheng et al.

INORGANIC CHEMISTRY (2019)

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Article Chemistry, Multidisciplinary

Supramolecular Iron Metallocubanes Exhibiting Site-Selective Thermal and Light-Induced Spin-Crossover

Izar Capel Berdiell et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Chemistry, Inorganic & Nuclear

A mixed-spin spin-crossover thiozolylimine [Fe4L6]8+ cage

Li Li et al.

DALTON TRANSACTIONS (2019)

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Review Chemistry, Inorganic & Nuclear

Spin-crossover in iron(ii)-Schiff base complexes

Kuppusamy Senthil Kumar et al.

DALTON TRANSACTIONS (2019)

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Article Chemistry, Inorganic & Nuclear

Dinuclear helicate and tetranuclear cage assembly using appropriately designed ditopic triazole-azine ligands

Sandhya Singh et al.

DALTON TRANSACTIONS (2019)

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Article Chemistry, Inorganic & Nuclear

Electron-Deficient Pyridylimines: Versatile Building Blocks for Functional Metallosupramolecular Chemistry

Niklas Struch et al.

INORGANIC CHEMISTRY (2018)

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Article Chemistry, Multidisciplinary

Spin-state switching in Fe(II) helicates and cages

Anna J. McConnell

SUPRAMOLECULAR CHEMISTRY (2018)

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Article Chemistry, Multidisciplinary

Micromachining-Compatible, Facile Fabrication of Polymer Nanocomposite Spin Crossover Actuators

Maria D. Manrique-Juarez et al.

ADVANCED FUNCTIONAL MATERIALS (2018)

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Review Chemistry, Inorganic & Nuclear

Spin crossover in homoleptic Fe(II) imidazolylimine complexes

Hayley S. Scott et al.

COORDINATION CHEMISTRY REVIEWS (2018)

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Article Chemistry, Physical

Iron(II) and Iron(III) Spin Crossover: Toward an Optimal Density Functional

Oliver S. Siig et al.

JOURNAL OF PHYSICAL CHEMISTRY A (2018)

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Article Chemistry, Multidisciplinary

Spin State Chemistry: Modulation of Ligand pK(a) by Spin State Switching in a [2x2] Iron(II) Grid-Type Complex

Sebastien Dhers et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

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Article Chemistry, Multidisciplinary

Encapsulation of a Cr-III Single-Ion Magnet within an Fe-II Spin-Crossover Supramolecular Host

Mohanad Darawsheh et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

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Review Chemistry, Multidisciplinary

Spin crossover in discrete polynuclear iron(ii) complexes

Ross W. Hogue et al.

CHEMICAL SOCIETY REVIEWS (2018)

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Article Chemistry, Multidisciplinary

Deciphering the Influence of Meridional versus Facial Isomers in Spin Crossover Complexes

Timothee Lathion et al.

CHEMISTRY-A EUROPEAN JOURNAL (2018)

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Editorial Material Chemistry, Multidisciplinary

Preface and introduction

Jacqueline Zarembowitch et al.

COMPTES RENDUS CHIMIE (2018)

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Article Chemistry, Inorganic & Nuclear

Guest-Adaptable Spin Crossover Properties in a Dinuclear Species Underpinned by Supramolecular Interactions

John E. Clements et al.

INORGANIC CHEMISTRY (2018)

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Article Chemistry, Inorganic & Nuclear

Small Structural Variations Have Large Effects on the Assembly Properties and Spin State of Room Temperature High Spin Fe(II) Inninopyridine Cages

Tabitha F. Miller et al.

INORGANIC CHEMISTRY (2018)

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Article Chemistry, Inorganic & Nuclear

Carboxylic Acid Functionalized Spin-Crossover Iron(II) Grids for Tunable Switching and Hybrid Electrode Fabrication

Takuya Shiga et al.

INORGANIC CHEMISTRY (2018)

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Article Chemistry, Multidisciplinary

Tetrahedral metal-organic cages with cube-like cavities for selective encapsulation of fullerene guests and their spin-crossover properties

Wang-Kang Han et al.

CHEMICAL COMMUNICATIONS (2018)

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Article Chemistry, Multidisciplinary

Spin Crossover Nanomaterials: From Fundamental Concepts to Devices

Gabor Molnar et al.

ADVANCED MATERIALS (2018)

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Article Chemistry, Multidisciplinary

Dinuclear Iron(II) Spin-Crossover Compounds: A Theoretical Study

Quan Manh Phung et al.

CHEMISTRY-A EUROPEAN JOURNAL (2018)

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Article Chemistry, Inorganic & Nuclear

A Family of Octahedral Magnetic Molecules Based on [NbIV(CN)8]4-

Miroslaw Arczynski et al.

INORGANIC CHEMISTRY (2017)

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Article Chemistry, Inorganic & Nuclear

Iron(II) Complexes of 2,4-Dipyrazolyl-1,3,5-triazine Derivatives-The Influence of Ligand Geometry on Metal Ion Spin State

Izar Capel Berdiell et al.

INORGANIC CHEMISTRY (2017)

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Article Chemistry, Multidisciplinary

Subcomponent Exchange Transforms an FeII4L4 Cage from High- to Low-Spin, Switching Guest Release in a Two-Cage System

Anna J. McConnell et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

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Article Chemistry, Inorganic & Nuclear

A probe of steric ligand substituent effects on the spin crossover of Fe(II) complexes

C. Bartual-Murgui et al.

INORGANIC CHEMISTRY FRONTIERS (2017)

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Article Chemistry, Multidisciplinary

The role of symmetry breaking in the structural trapping of light-induced excited spin states

Rafal Kulmaczewski et al.

CHEMICAL COMMUNICATIONS (2017)

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Article Chemistry, Inorganic & Nuclear

High-Temperature Wide Thermal Hysteresis of an Iron(II) Dinuclear Double Helicate

Shiori Hora et al.

INORGANICS (2017)

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Article Chemistry, Multidisciplinary

A Magneto-optical Molecular Device: Interplay of Spin Crossover, Luminescence, Photomagnetism, and Photochromism

Marta Estrader et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

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Review Chemistry, Inorganic & Nuclear

Emerging trends in spin crossover (SCO) based functional materials and devices

Kuppusamy Senthil Kumar et al.

COORDINATION CHEMISTRY REVIEWS (2017)

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Article Chemistry, Inorganic & Nuclear

Modulation of the FeII spin crossover effect in the pentadecanuclear {Fe9[M(CN)8]6} (M = Re, W) clusters by facial coordination of tridentate polyamine ligands

Szymon Chorazy et al.

DALTON TRANSACTIONS (2017)

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Article Chemistry, Multidisciplinary

An Octanuclear Metallosupramolecular Cage Designed To Exhibit Spin-Crossover Behavior

Niklas Struch et al.

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