Supramolecular Coordination Cages for Artificial Photosynthesis and Synthetic Photocatalysis

Article Chemistry, Multidisciplinary

Dye-loaded metal-organic helical capsules applied to the combination of photocatalytic H2S splitting and nitroaromatic hydrogenation

Yang Yang et al.

Summary: Two dye-loaded metal-organic capsules with different spatial sizes and functional groups were used to simulate enzymatic substrate activation for hydrogenation of nitroarenes, following the kinetics of the Michaelis-Menten mechanism.

CHEMICAL COMMUNICATIONS (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Alkoxy Radicals See the Light: New Paradigms of Photochemical Synthesis

Liang Chang et al.

Summary: This review comprehensively summarizes the recent progress in alkoxy radical-mediated transformations under visible light irradiation. The mechanisms of alkoxy radical generation and their impact on synthetic utilizations are discussed. The catalytic generation of alkoxy radicals from abundant alcohols is still in the early stage, but holds great potential.

CHEMICAL REVIEWS (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Photoinduced Organocatalyzed Atom Transfer Radical Polymerization (O-ATRP): Precision Polymer Synthesis Using Organic Photoredox Catalysis

Daniel A. Corbin et al.

Summary: The development of photoinduced organocatalyzed atom transfer radical polymerization (O-ATRP) has attracted significant attention due to its ability to produce well-defined polymers under mild reaction conditions using organic photoredox catalysts. However, further investigation is needed to address the limitations of this method and expand its capabilities and applications.

CHEMICAL REVIEWS (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Applications of Halogen-Atom Transfer (XAT) for the Generation of Carbon Radicals in Synthetic Photochemistry and Photocatalysis

Fabio Julia et al.

Summary: This review focuses on the importance and application of halogen-atom transfer (XAT) in synthetic chemistry, particularly its impact on photochemistry and photocatalysis. The material is organized based on mechanistic aspects and the nature of reagents used in halogen abstraction. The aim is to provide a general overview of fundamental concepts and key agents involved in XAT processes to facilitate the development of new synthetic radical strategies.

CHEMICAL REVIEWS (2022)

Add to Collection

Editorial Material Chemistry, Multidisciplinary

Introduction: Photochemical Catalytic Processes

Paolo Melchiorre

CHEMICAL REVIEWS (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis

Amy Y. Chan et al.

Summary: The merger of photoredox catalysis with transition metal catalysis, known as metallaphotoredox catalysis, has become an important part of synthetic methodology. It combines the bond formation capability of transition metal catalysis with the utility of photoinduced electron and energy transfer processes. Photocatalytic substrate activation allows the involvement of simple starting materials in metal-mediated bond-forming processes, while electron or energy transfer with organometallic intermediates provides a complementary activation mode to traditional catalytic platforms.

CHEMICAL REVIEWS (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Photoredox-Catalyzed C-H Functionalization Reactions

Natalie Holmberg-Douglas et al.

Summary: The fields of C-H functionalization and photoredox catalysis have gained significant interest and utility in various scientific disciplines. This review focuses on the use of photoredox catalysis in C-H functionalization reactions, highlighting both inorganic/organometallic and organic-based photoredox catalytic systems. The subdivision by reaction class (sp(2) or sp(3) C-H functionalization) provides perspective and tactical strategies for synthetic applications.

CHEMICAL REVIEWS (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Strategies to Generate Nitrogen-centered Radicals That May Rely on Photoredox Catalysis: Development in Reaction Methodology and Applications in Organic Synthesis

Kitae Kwon et al.

Summary: This review is a guide for chemists engaged in target-oriented synthesis, summarizing the recent methods and applications of generating nitrogen-centered radicals through photocatalysis. The mild conditions of this approach enable its wide applications in synthesizing various small molecules, highlighting its tremendous utility.

CHEMICAL REVIEWS (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Photochemical and Electrochemical Applications of Proton-Coupled Electron Transfer in Organic Synthesis

Philip R. D. Murray et al.

Summary: This article presents a comprehensive review of the photochemical and electrochemical applications of multi-site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCET involves the simultaneous exchange of an electron and a proton in a non-classical redox mechanism, offering opportunities for the direct generation of synthetically useful free radical intermediates from common organic functional groups. The article provides an introduction to MS-PCET and a practitioner's guide to reaction design, focusing on the unique energetic and selectivity features of this reaction class. It also discusses various oxidative and reductive PCET activations for bond homolysis and the applications of MS-PCET in asymmetric catalysis, materials, and device applications.

CHEMICAL REVIEWS (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Chiral Photocatalyst Structures in Asymmetric Photochemical Synthesis

Matthew J. Genzink et al.

Summary: Asymmetric photocatalysis is a major research topic in contemporary synthetic organic chemistry. However, the discovery of general strategies for highly enantioselective photochemical reactions has been a recent development, leading to a somewhat limited variety of stereocontrolled photoreactions. This review summarizes the chiral catalyst structures that have been studied for solution-phase asymmetric photochemistry, providing insight into the logic required for highly effective stereocontrolled photocatalysis.

CHEMICAL REVIEWS (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Photocatalysis in the Life Science Industry

Lisa Candish et al.

Summary: This Review summarizes the contributions to the field of photocatalysis from the life science industry, including the development of synthetic methodologies and strategic applications in chemical synthesis. The state-of-the-art in photoreactor technology and the effective upscaling of photocatalytic reactions are also discussed.

CHEMICAL REVIEWS (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Aryl Transfer Strategies Mediated by Photoinduced Electron Transfer

Anthony R. Allen et al.

Summary: This review summarizes the progress in radical aryl migration enabled by photochemical methods, particularly photoredox catalysis, since 2015. Special attention is given to describing the scope, mechanism, and synthetic applications of each method.

CHEMICAL REVIEWS (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Photons or Electrons? A Critical Comparison of Electrochemistry and Photoredox Catalysis for Organic Synthesis

Nicholas E. S. Tay et al.

Summary: Redox processes play a crucial role in synthetic methods involving electrochemistry and photoredox catalysis. Both approaches offer access to high energy intermediates that allow for unconventional bond formations. However, while they provide similar intermediates, electrochemistry and photoredox catalysis differ in their physical chemistry principles. Understanding these differences is essential for designing new transformations and bond disconnections.

CHEMICAL REVIEWS (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Visible Light-Induced Transition Metal Catalysis

Kelvin Pak Shing Cheung et al.

Summary: Visible light-induced transition metal catalysis has emerged as an important development in organic photocatalysis, leading to unprecedented transformations and improvements of known reactions. This method utilizes a single catalytic cycle to harness photon energy, and synergistically combines catalyst-substrate interaction with photoinduced processes.

CHEMICAL REVIEWS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Rhodium-Based Metal-Organic Polyhedra Assemblies for Selective CO2 Photoreduction

Ashta C. Ghosh et al.

Summary: By immobilizing dirhodium paddlewheels within metal-organic polyhedra (MOP) and assembling them into supramolecular structures, the catalytic properties of the catalysts are enhanced, particularly for the selective photochemical reduction of carbon dioxide to formic acid. The supramolecular structures exhibit higher catalytic activity per Rh atom compared to the molecular sub-unit Rh-MOP or Rh-metal-organic framework (Rh-MOF), with high turnover frequencies and production rates.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Add to Collection

Article Biochemistry & Molecular Biology

Proton-controlled Action of an Imidazole as Electron Relay in a Photoredox Triad

Philipp Gotico et al.

Summary: Electron relays play a crucial role in light-induced catalytic reactions. Inserting electron relays reduces energy transfer quenching and enables unidirectional electron flow. This is essential for charge accumulation in catalysis.

PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Zirconium Metal-Organic Cages: Synthesis and Applications

El-Sayed M. El-Sayed et al.

Summary: In recent years, the synthesis of porous crystalline materials, such as metal-organic frameworks and organic cages, with tunable atomic structures has shown great potential in various fields. Discrete metal-organic cages, in particular, have attracted attention due to their molecular nature and solution-processability. The zirconium MOC family, known for its robust nature and high hydrothermal stability, holds significant potential for expanding applications. This Account highlights recent advances in synthesizing zirconium MOCs and their applications in higher-dimensional frameworks.

ACCOUNTS OF CHEMICAL RESEARCH (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Visible-Light-Mediated Modification and Manipulation of Biomacromolecules

Vivian M. Lechner et al.

Summary: Chemically modified biomacromolecules play a crucial role in chemical biology. Visible-light-induced photochemical approaches have emerged as an effective method to modify biomacromolecules, offering mild reaction conditions and precise control. These methods can be used to modify native functional groups as well as non-native, bioorthogonal functional groups, allowing manipulation of biomacromolecule activity.

CHEMICAL REVIEWS (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Strategic Use of Visible-Light Photoredox Catalysis in Natural Product Synthesis

Spencer P. Pitre et al.

Summary: Recent progress in visible light photocatalytic reactions has revitalized the use of photochemistry in the synthesis of complex organic molecules. This review examines total syntheses published by the end of 2020 that employ visible-light photoredox catalysis, providing insights on functional group compatibility and synthetic strategies.

CHEMICAL REVIEWS (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Direct Photocatalyzed Hydrogen Atom Transfer (HAT) for Aliphatic C-H Bonds Elaboration

Luca Capaldo et al.

Summary: Direct photocatalyzed hydrogen atom transfer (d-HAT) is a preferred method for the synthesis of aliphatic C-H bonds in organic compounds. Selective C-H bond elaboration can be achieved by choosing suitable hydrogen abstractors and reaction additives. This review provides a comprehensive survey of the synthetic applications of photocatalyzed d-HAT.

CHEMICAL REVIEWS (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Enantioselective Photochemical Reactions Enabled by Triplet Energy Transfer

Johannes Grosskopf et al.

Summary: This review provides a comprehensive survey on enantioselective photochemical reactions achieved through triplet sensitization. It is shown that highly selective enantioselective photochemical reactions can be achieved by using appropriate chiral sensitizers or a dual catalytic approach.

CHEMICAL REVIEWS (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Advances in the E → Z Isomerization of Alkenes Using Small Molecule Photocatalysts

Tomas Nevesely et al.

Summary: Geometrical E → Z alkene isomerization, a critical topic in organic photochemistry, has seen significant advancements in recent years. By utilizing energy transfer catalysis, directed isomerization of alkenes can be achieved. This review summarizes the progress in the field of geometric alkene isomerization enabled by energy transfer catalysis from 2000 to 2020, and discusses the reaction mechanisms, induction models, and applications in total synthesis and regioselective reactions.

CHEMICAL REVIEWS (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Technological Innovations in Photochemistry for Organic Synthesis: Flow Chemistry, High-Throughput Experimentation, Scale-up, and Photoelectrochemistry

Laura Buglioni et al.

Summary: This paper provides a comprehensive overview of the exciting technological advances in the field of photoinduced chemical transformations, including flow chemistry, high-throughput experimentation, reactor design and scale-up, and the combination of photo- and electro-chemistry.

CHEMICAL REVIEWS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Aqueous Biphasic Dye-Sensitized Photosynthesis Cells for TEMPO-Based Oxidation of Glycerol

Didjay F. Bruggeman et al.

Summary: This study reports a dye-sensitized photoelectrochemical cell that is capable of oxidizing glycerol and producing hydrogen. The use of a redox-gel layer with a high potential dye-sensitized mesoporous TiO2 photoanode protects the photoanode from degradation and significantly improves the conversion rate of glycerol. The redox-gel protected photoanode also demonstrates stable photocurrent over extended periods of continuous operation.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Add to Collection

Review Biochemistry & Molecular Biology

Photoinduced Electron Transfer in Organized Assemblies-Case Studies

Antonio Santoro et al.

Summary: In this review, recent results of photoinduced electron transfer processes in specifically designed assembled architectures are discussed. A convenient method to study these systems is described, aiming to understand the rules behind light-induced charge-separated states and subsequent decay, and to serve as a tutorial for young researchers. The review covers assembled systems of covalent or supramolecular nature, as well as functional multicomponent systems for light-to-chemical energy conversion.

MOLECULES (2022)

Add to Collection

Review Chemistry, Physical

Computational Modeling of Supramolecular Metallo-organic Cages-Challenges and Opportunities

Tomasz K. Piskorz et al.

Summary: This review discusses the key molecular principles governing the design of functional metallo-organic cages and reviews computational protocols, highlighting the importance of combining computational and experimental efforts.

ACS CATALYSIS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Source of Rate Acceleration for Carbocation Cyclization in Biomimetic Supramolecular Cages

Quynh Nhu N Nguyen et al.

Summary: The results of the study show that polyanionic gallium-based cages can accelerate the cyclization reactions of pentadienyl alcohols due to substrate cage interactions, preferential binding of reactive conformations of substrate/H3O+ pairs, and increased substrate basicity.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Add to Collection

Article Chemistry, Multidisciplinary

An Organo-Palladium Host Built from a Dynamic Macrocyclic Ligand: Adaptive Self-Assembly, Induced-Fit Guest Binding, and Catalysis

Dan-Ni Yan et al.

Summary: The adaptive self-assembly and host-guest catalysis of a new water-soluble organo-palladium host are reported. The host undergoes conformational changes upon guest binding, allowing for efficient and selective catalysis.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Encapsulating electron-deficient dyes into metal-organic capsules to achieve high reduction potentials

Jiayou Yuan et al.

Summary: In this work, a metal-organic capsule was assembled by incorporating electron-deficient dyes into electron-rich pseudo-cubic capsules, creating an efficient artificial enzyme-mimicking supramolecular system for photocatalytic reduction reactions. The confined space of the host facilitated intimate contact between the electron-deficient dyes and the electron-rich host walls, promoting photoinduced electron transfer. The study achieved high yields in a short reaction time, demonstrating potential applications in solar energy conversion and enzyme-mimicking catalysis.

DALTON TRANSACTIONS (2022)

Add to Collection

Review Chemistry, Inorganic & Nuclear

Recent progress in homogeneous light-driven hydrogen evolution using first-row transition metal catalysts

Agostina Mazzeo et al.

Summary: Researchers focus on designing, preparing, and testing efficient catalytic systems based on first-row transition metals for homogeneous light-driven hydrogen evolution. Hundreds of molecular HER photocatalysts containing earth-abundant metals and various ligands have been reported and tested recently, aiming to contribute to the development of efficient solar energy devices for H2 generation as a green fuel. This work aims to update the community on the latest advances in this rapidly growing field, with a focus on systems reported between 2016 and 2020.

INORGANICA CHIMICA ACTA (2021)

Add to Collection

Review Biochemistry & Molecular Biology

Photo-biocatalytic Cascades: Combining Chemical and Enzymatic Transformations Fueled by Light

Fatma Feyza Ozgen et al.

Summary: The use of light to drive biocatalytic reactions presents challenges such as incompatibility between enzymes and photocatalysts, as well as the formation of reactive radicals upon illumination. Overcoming these challenges requires the development of more effective strategies and methods.

CHEMBIOCHEM (2021)

Add to Collection

Article Chemistry, Physical

Effects of Photosensitizers and Reaction Media on Light-Driven Water Oxidation with Trinuclear Ruthenium Macrocycles

Ana-Lucia Meza-Chincha et al.

Summary: The study revealed that the process of photocatalytic water oxidation is influenced by various factors such as the choice of photosensitizer, reaction media, buffer concentration, light intensity, and sensitizer concentration. The catalytic activities of Ru macrocycles are not only limited by their intrinsic catalytic activities, but also by the efficiency of photogeneration of oxidant PS(+) and its ability to act as an oxidizing agent to the catalysts, both of which strongly depend on the choice of photosensitizer and the amount of employed organic co-solvent.

CHEMPHOTOCHEM (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Guest Encapsulation within Surface-Adsorbed Self-Assembled Cages

Hugh P. Ryan et al.

Summary: A method for immobilizing coordination cages on alumina has been reported, allowing for the encapsulation and separation of guest and non-guest molecules. Quantification of cage loadings and guest displacement assays demonstrate the retained ability of the adsorbed cages.

ADVANCED MATERIALS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Coal-Tar Dye-based Coordination Cages and Helicates

Irene Regeni et al.

Summary: This study introduces a strategy to incorporate four members of the classic coal-tar dye family into [Pd2L4] self-assemblies, investigating their performance in different ligands and color ranges, showing potential applications in chiroptical recognition, photo-redox catalysis, and optical materials. The results demonstrate different behaviors of the self-assemblies based on this new ligand class, such as chiral induction, binding modes distinction, and rearrangement to new structures.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Add to Collection

Article Chemistry, Multidisciplinary

A Calix[4]arene-Based Cyclic Dinuclear Ruthenium Complex for Light-Driven Catalytic Water Oxidation

Niklas Noll et al.

Summary: The cyclic dinuclear ruthenium complex with oligo(ethylene glycol)-functionalized axial calix[4]arene ligands showed enhanced catalytic activity in water oxidation compared to the mononuclear reference compound. The kinetic studies revealed a unimolecular water nucleophilic attack mechanism for this novel dinuclear water oxidation catalyst, demonstrating its potential for artificial photosynthesis. The photocatalytic performance of this complex was reported to be the highest among Ru(bda) complexes, indicating its promising application in the field of water oxidation research.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

Add to Collection

Review Chemistry, Inorganic & Nuclear

Photoresponse within dye-incorporated metal-organic architectures

Yang Jiao et al.

Summary: Recognition, involving weak non-covalent interactions, is crucial in biological systems for enzyme-substrate binding. Chemists have developed recognition systems based on supramolecular metal-organic architectures, which offer large cavities for selective binding and diverse interactions with analytes. Optimal detection relies on the optical signals from the recognition of host and analyte molecules within the confined spaces of metal-organic hosts through electron/energy transfer processes, redox reactions, or other mechanisms.

COORDINATION CHEMISTRY REVIEWS (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Supramolecular Strategies for the Recycling of Homogeneous Catalysts

Bo Zhang et al.

Summary: Supramolecular approaches are increasingly important in the development of homogeneous catalysts and the recycling of metal-based catalysts. Non-covalent anchoring of catalysts allows for easy recovery and reuse, while supramolecular chemistry can generate support materials with catalytic function, improving recyclability and stability of catalytic systems.

CHEMISTRY-AN ASIAN JOURNAL (2021)

Add to Collection

Article Chemistry, Physical

A high-efficiency dye-sensitized Pt(II) decorated metal-organic cage for visible-light-driven hydrogen production

Chunqing Ji et al.

Summary: Platinum complexes have been widely used as catalysts for hydrogen production from water due to their high work function and redox potential. The functionalized Zr-Bpydc-PtCl2 MOCs show good stability and high photocatalytic efficiency in producing H-2, indicating the promising approach of integrating catalyst molecules into MOCs for improving the efficiency of water hydrogen production.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Add to Collection

Article Chemistry, Applied

Overview and challenges of the photolytic and photocatalytic splitting of H2S

Habeebllah Oladipo et al.

Summary: This article reviews studies on the photolytic and photocatalytic splitting of H2S to generate hydrogen, comparing the economic potential and kinetics of gaseous and aqueous phase reactions. Higher efficiency has been achieved with MnS photocatalysts compared to CdS. Future work is needed to address challenges such as photo-corrosion in order to advance light-driven H2S splitting for hydrogen production.

CATALYSIS TODAY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Structure-Activity Relationship for Di- up to Tetranuclear Macrocyclic Ruthenium Catalysts in Homogeneous Water Oxidation

Dorothee Schindler et al.

Summary: The catalytic activities of di- and tetranuclear Ru(bda) macrocycles in homogeneous water oxidation depend on their size, with the largest tetranuclear catalyst showing the highest efficiency. Turnover frequencies per Ru unit have increased from di- to tetranuclear macrocycles, indicating a clear structure-activity relationship for this novel class of macrocyclic water oxidation catalysts.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Photocatalysis in Supramolecular Fluorescent Metallacycles and Metallacages

Hong-Yu Lin et al.

Summary: This review highlights recent advances in photocatalysis using supramolecular fluorescent metallacycles and metallacages. It discusses the utilization of metallacycles skeletons and the impact of fluorescence-resonance energy transfer on photocatalysis, as well as summarizes the use of ligands decorated with organic chromophores or redox metal sites in metallacages as photocatalysts.

CHEMISTRY-AN ASIAN JOURNAL (2021)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Cobalt-Based Metal-Organic Cages for Visible-Light-Driven Water Oxidation

Zi-Ye Chen et al.

Summary: A series of Co-based metal-organic cages were prepared for photoinduced water oxidation, with MOC-1 showing the highest catalytic activity. Isotope experiments confirmed that molecular oxygen was produced from water oxidation, and the process was initiated by electron transfer from [Ru(bpy)(3)](2+)* to Na2S2O8.

INORGANIC CHEMISTRY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Photooxidase Mimicking with Adaptive Coordination Molecular Capsules

Dan-Ni Yan et al.

Summary: The adaptive molecular capsule with structural changes upon substrate binding allows for efficient photocatalysis, paving the way for artificial systems mimicking enzyme catalysis. The capsule undergoes quantitative transformation when substrates bind to its hydrophobic cavity, facilitating aerobic photooxidation for the sulfide guests under mild conditions. Through the transformable nature of the catalyst and the hydrophilicity of the sulfoxide product, desired turnover numbers and product selectivity have been achieved.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Add to Collection

Article Chemistry, Physical

Single Metal-Organic Cage Decorated with an Ir(III) Complex for CO2 Photoreduction

Xiangjuan Qi et al.

Summary: A novel single molecular cage of Ir(III) complex-decorated Zr-MOC has been proposed for CO2 photoreduction, showing high reactivity, selectivity, and apparent quantum yield. The catalytic center is the Ir(III) complex, while the -NH2 in the framework plays a synergetic role in stabilizing the transition state and CO2 adducts, leading to superior performance compared to classical metal-organic framework counterparts.

ACS CATALYSIS (2021)

Add to Collection

Article Chemistry, Physical

The roles of polyoxometalates in photocatalytic reduction of carbon dioxide

J. Gu et al.

Summary: This review discusses the recent progress of POMs and POM-based photocatalysts for CO2 reduction, highlighting the roles of POMs in photocatalytic reactions and providing important guidance for the design of high-efficiency photocatalysts.

MATERIALS TODAY ENERGY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Recent advances and perspectives on supramolecular radical cages

Bin Huang et al.

Summary: Supramolecular radical chemistry, as an emerging interdisciplinary field, aims to combine traditional supramolecular chemistry and radical chemistry to create new molecules and materials. The focus has shifted towards the design and synthesis of supramolecular radical cages, exploring their unique properties and applications.

CHEMICAL SCIENCE (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Cavity-promotion by pillar[5]arenes expedites organic photoredox-catalysed reductive dehalogenations

Maximilian Schmidt et al.

Summary: The efficiency of photo-induced electron transfer in photoredox catalysis can be limited by diffusional collision of excited catalyst and substrate. In this study, cavity-bound photoredox catalysts are introduced to preassociate substrates, leading to significantly shortened reaction times. A proof of concept reaction using pillar[5]arene as a cavity and phenothiazine as a catalyst showed promising results.

CHEMICAL COMMUNICATIONS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

An Ir3L2 complex with anion binding pockets: photocatalytic E-Z isomerization via molecular recognition

Haruka Sunohara et al.

Summary: By constructing a self-assembled photoactive Ir(iii) cage-shaped complex with anion binding pockets, efficient catalysis of visible-light-induced E-Z isomerization of an anionic styrene derivative is achieved.

CHEMICAL COMMUNICATIONS (2021)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Coordination-driven self-assembly of anthraquinone-based metal-organic cages for photocatalytic selective [2+2] cycloaddition

Yao Jin et al.

Summary: This study introduces anthraquinone-based metal-organic cages (MOCs) for efficient synthesis of cyclobutanes through [2 + 2] photocycloaddition. The MOCs, constructed via coordination-driven self-assembly strategy, exhibit high efficiency and recyclability in the reaction. The confined space provided by the cage catalysts leads to enhanced selectivity compared to free anthraquinone catalyst.

DALTON TRANSACTIONS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Self-assembled metallasupramolecular cages towards light harvesting systems for oxidative cyclization

Atul Kumar et al.

Summary: The study demonstrates the synthesis of three molecular cages for efficient light harvesting in aqueous medium, with high molar extinction coefficients and large Stokes shifts. These cages exhibit aggregation-induced emission (AIE) in water/MeCN mixture and solid state, and can be used as donors for artificial light harvesting systems with high energy efficiency and good antenna effect. The harvested energy from the light harvesting systems was successfully utilized for visible light induced photo-oxidative cross coupling cyclization of N,N-dimethylaniline with N-alkyl/aryl maleimides in aqueous acetonitrile with significant enhancement in yields.

CHEMICAL SCIENCE (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Increasing structural and functional complexity in self-assembled coordination cages

Sonja Pullen et al.

Summary: Progress in metallo-supramolecular chemistry has led to the synthesis of functional nano systems and intelligent materials, with a focus on structures such as helicates, grids, links, knots, spheres, and cages. These assemblies, with nano-scale cavities, offer potential for applications as selective receptors and confined reaction environments. Recent advances include the incorporation of dedicated functionality like catalytic centers and photoswitches, allowing for stimuli control.

CHEMICAL SCIENCE (2021)

Add to Collection

Article Chemistry, Physical

Photochemistry using a host-guest charge transfer paradigm: DMABN as a dynamical probe of ground and excited states†

Rahul Gera et al.

Summary: The study focuses on photoexciting charge transfer transitions arising from host-guest interactions in a confined environment, and the investigation of heterogeneity of guest orientations and ensuing charge transfer dynamics, highlighting challenges for using molecular cages as photocatalytic reaction vessels.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Supramolecular strategies in artificial photosynthesis

Tom Keijer et al.

Summary: Artificial photosynthesis aims to convert solar power into chemical fuel for sustainable energy production, with three fundamental steps including light harvesting, charge-separation, and redox catalysis. Supramolecular chemistry, with its ability to control molecular components precisely through self-assembly processes, can provide important tools for preparing, integrating, and optimizing artificial photosynthetic devices.

CHEMICAL SCIENCE (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Synthetic Photoelectrochemistry

Joshua P. Barham et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Visible-Light Photocatalysis of Asymmetric [2+2] Cycloaddition in Cage-Confined Nanospace Merging Chirality with Triplet-State Photosensitization

Jing Guo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Add to Collection

Article Chemistry, Multidisciplinary

The Redox Coupling Effect in a Photocatalytic RuII-PdII Cage with TTF Guest as Electron Relay Mediator for Visible-Light Hydrogen-Evolving Promotion

Kai Wu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Add to Collection

Review Chemistry, Inorganic & Nuclear

Recent progress in the development of transition-metal based photoredox catalysts

Felix Glaser et al.

COORDINATION CHEMISTRY REVIEWS (2020)

Add to Collection

Review Chemistry, Inorganic & Nuclear

Analysis of electrocatalytic metal-organic frameworks

Brian D. McCarthy et al.

COORDINATION CHEMISTRY REVIEWS (2020)

Add to Collection

Article Chemistry, Physical

Promoting visible-light-driven hydrogen production of a zirconium-based metal-organic polyhedron decorated by platinum nanoparticles with different spatial locations

Min Sun et al.

CATALYSIS COMMUNICATIONS (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Pillar[5]arene based conjugated macrocycle polymers with unique photocatalytic selectivity

Hui Qiang et al.

CHINESE CHEMICAL LETTERS (2020)

Add to Collection

Review Nanoscience & Nanotechnology

Chemical reactivity under nanoconfinement

Angela B. Grommet et al.

NATURE NANOTECHNOLOGY (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Dual-Emissive Platinum(II) Metallacage with a Sensitive Oxygen Response for Imaging of Hypoxia and Imaging-Guided Chemotherapy

Huangtianzhi Zhu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Add to Collection

Article Multidisciplinary Sciences

Cage-confined photocatalysis for wide-scope unusually selective [2+2] cycloaddition through visible-light triplet sensitization

Jing-Si Wang et al.

NATURE COMMUNICATIONS (2020)

Add to Collection

Review Chemistry, Multidisciplinary

Electrochemical Oxidation of Lignin and Waste Plastic

Robert S. Weber et al.

ACS OMEGA (2020)

Add to Collection

Review Chemistry, Physical

Advances in supramolecular host-mediated reactivity

Mariko Morimoto et al.

NATURE CATALYSIS (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Heterogeneous Supramolecular Catalysis through Immobilization of Anionic M4L6 Assemblies on Cationic Polymers

Hiroyuki Miyamura et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Add to Collection

Review Chemistry, Multidisciplinary

Recent developments in the construction and applications of platinum-based metallacycles and metallacages via coordination

Yan Sun et al.

CHEMICAL SOCIETY REVIEWS (2020)

Add to Collection

Review Chemistry, Physical

MOF-mimetic molecules: carboxylate-based supramolecular complexes as molecular metal-organic framework analogues

Gerald E. Decker et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Add to Collection

Article Chemistry, Multidisciplinary

A highly active, robust photocatalyst heterogenized in discrete cages of metal-organic polyhedra for CO2 reduction

Hyeon Shin Lee et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Electrocatalytic proton and water reduction by a Co(III) polypyridyl complex

Surabhi Rai et al.

POLYHEDRON (2019)

Add to Collection

Article Multidisciplinary Sciences

Ultrafast photoactivation of C-H bonds inside water-soluble nanocages

Ankita Das et al.

SCIENCE ADVANCES (2019)

Add to Collection

Review Chemistry, Multidisciplinary

Strategies for binding multiple guests in metal-organic cages

Felix J. Rizzuto et al.

NATURE REVIEWS CHEMISTRY (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Demethylenation of Cyclopropanes via Photoinduced Guest-to-Host Electron Transfer in an M6L4 Cage

William Cullen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Add to Collection

Review Chemistry, Multidisciplinary

The development of molecular water oxidation catalysts

Roc Matheu et al.

NATURE REVIEWS CHEMISTRY (2019)

Add to Collection

Review Chemistry, Multidisciplinary

Water Oxidation Catalysts for Artificial Photosynthesis

Sheng Ye et al.

ADVANCED MATERIALS (2019)

Add to Collection

Review Chemistry, Multidisciplinary

Photochemical Properties of Host-Guest Supramolecular Systems with Structurally Confined Metal-Organic Capsules

Xu Jing et al.

ACCOUNTS OF CHEMICAL RESEARCH (2019)

Add to Collection

Review Chemistry, Physical

Gold Catalysis in (Supra)Molecular Cages to Control Reactivity and Selectivity

Anne C. H. Jans et al.

CHEMCATCHEM (2019)

Add to Collection

Article Chemistry, Multidisciplinary

An Amine-Functionalized Zirconium Metal-Organic Polyhedron Photocatalyst with High Visible-Light Activity for Hydrogen Production

Min Sun et al.

CHEMISTRY-A EUROPEAN JOURNAL (2019)

Add to Collection

Review Chemistry, Inorganic & Nuclear

Chiral metal-organic cages/containers (MOCs): From structural and stereochemical design to applications

Mei Pan et al.

COORDINATION CHEMISTRY REVIEWS (2019)

Add to Collection

Review Chemistry, Inorganic & Nuclear

Catalytic properties of chemical transformation within the confined pockets of Werner-type capsules

Liang Zhao et al.

COORDINATION CHEMISTRY REVIEWS (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Encapsulation of Organic Dyes within an Electron-Deficient Redox Metal-Organic Tetrahedron for Photocatalytic Proton Reduction

Hailing Wang et al.

ISRAEL JOURNAL OF CHEMISTRY (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Photochemical hydrogen evolution from water by a 1D-network of octahedral Ni6L8 cages

Kilaparthi Sravan Kumar et al.

CHEMICAL COMMUNICATIONS (2019)

Add to Collection

Proceedings Paper Energy & Fuels

Thermodynamic Analysis of the Efficiency of Photoelectrochemical CO2 Reduction to Ethanol

Evangelos Kalamaras et al.

INNOVATIVE SOLUTIONS FOR ENERGY TRANSITIONS (2019)

Add to Collection

Review Chemistry, Multidisciplinary

Photoactive supramolecular cages incorporating Ru(ii) and Ir(iii) metal complexes

Diego Rota Martir et al.

CHEMICAL COMMUNICATIONS (2019)

Add to Collection

Review Chemistry, Multidisciplinary

The chemistry of multi-component and hierarchical framework compounds

Liang Feng et al.

CHEMICAL SOCIETY REVIEWS (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Control over the synthesis of homovalent and mixed-valence cubic cobalt-imidazolate cages

Liang Liang et al.

CHEMICAL COMMUNICATIONS (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Negatively charged metal-organic hosts with cobalt dithiolene species: improving PET processes for light-driven proton reduction through host-guest electrostatic interactions

Junkai Cai et al.

CHEMICAL COMMUNICATIONS (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Self-Assembly of Chiral Metal-Organic Tetartoid

Dong Luo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Add to Collection

Article Chemistry, Multidisciplinary

Formal water oxidation turnover frequencies from MIL-101(Cr) anchored Ru(bda) depend on oxidant concentration

Asamanjoy Bhunia et al.

CHEMICAL COMMUNICATIONS (2018)

Add to Collection

Review Chemistry, Inorganic & Nuclear

Supramolecular iridium(III) assemblies

Diego Rota Martir et al.

COORDINATION CHEMISTRY REVIEWS (2018)

Add to Collection

Review Chemistry, Inorganic & Nuclear

Structure relationships between bis-monodentate ligands and coordination driven self-assemblies

Subhadeep Saha et al.

COORDINATION CHEMISTRY REVIEWS (2018)

Add to Collection

Article Chemistry, Multidisciplinary

Process-Tracing Study on the Postassembly Modification of Highly Stable Zirconium Metal-Organic Cages

Guoliang Liu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Add to Collection

Article Chemistry, Multidisciplinary

Water-Soluble Redox-Active Cage Hosting Polyoxometalates for Selective Desulfurization Catalysis

Li-Xuan Cai et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Add to Collection

Article Chemistry, Physical

Hammett Parameter in Microporous Solids as Macroligands for Heterogenized Photocatalysts

Florian M. Wisser et al.

ACS CATALYSIS (2018)

Add to Collection

Review Chemistry, Multidisciplinary

Coordination Cages Based on Bis(pyrazolylpyridine) Ligands: Structures, Dynamic Behavior, Guest Binding, and Catalysis

Michael D. Ward et al.

ACCOUNTS OF CHEMICAL RESEARCH (2018)

Add to Collection

Review Chemistry, Multidisciplinary

Site Isolation in Metal-Organic Frameworks Enables Novel Transition Metal Catalysis

Tasha Drake et al.

ACCOUNTS OF CHEMICAL RESEARCH (2018)

Add to Collection

Review Chemistry, Multidisciplinary

Ligand Template Strategies for Catalyst Encapsulation

Lukas J. Jongkind et al.

ACCOUNTS OF CHEMICAL RESEARCH (2018)

Add to Collection

Review Chemistry, Multidisciplinary

Energy transfer catalysis mediated by visible light: principles, applications, directions

Felix Strieth-Kalthoff et al.

CHEMICAL SOCIETY REVIEWS (2018)

Add to Collection

Article Chemistry, Multidisciplinary

Photocatalytic Hydrogen Evolution by a Synthetic [FeFe] Hydrogenase Mimic Encapsulated in a Porphyrin Cage

Sandra S. Nurttila et al.

CHEMISTRY-A EUROPEAN JOURNAL (2018)

Add to Collection

Review Chemistry, Multidisciplinary

Mixed-Ligand Metal-Organic Frameworks and Heteroleptic Coordination Cages as Multifunctional Scaffolds-A Comparison

Sonja Pullen et al.

ACCOUNTS OF CHEMICAL RESEARCH (2018)

Add to Collection

Review Chemistry, Multidisciplinary

Confinement Effects in Catalysis Using Well-Defined Materials and Cages

Valentinos Mouarrawis et al.

FRONTIERS IN CHEMISTRY (2018)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Light-driven Hydrogen Evolution from Water by a Tripodal Silane Based Co6IIL81 Octahedral Cage

Mahesh S. Deshmukh et al.

INORGANIC CHEMISTRY (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Redox-active copper triangles as an enzymatic molecular flask for light-driven hydrogen production

Liang Zhao et al.

RSC ADVANCES (2017)

Add to Collection

Article Multidisciplinary Sciences

DHPA-Containing Cobalt-Based Redox Metal-Organic Cyclohelicates as Enzymatic Molecular Flasks for Light-Driven H2 Production

Liang Zhao et al.

SCIENTIFIC REPORTS (2017)

Add to Collection

Article Chemistry, Physical

)Trinuclear Ruthenium Macrocycles: Toward Supramolecular Water Oxidation Catalysis in Pure Water

Valentin Kunz et al.

ACS ENERGY LETTERS (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Rational Design Rules for Molecular Water Oxidation Catalysts based on Scaling Relationships

Joeri Hessels et al.

CHEMISTRY-A EUROPEAN JOURNAL (2017)

Add to Collection

Review Chemistry, Multidisciplinary

O-O bond formation in ruthenium-catalyzed water oxidation: single-site nucleophilic attack vs. O-O radical coupling

David W. Shaffer et al.

CHEMICAL SOCIETY REVIEWS (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Photochemical H2 Evolution Catalyzed by Porphyrin-based Cubic Cages Singly and Doubly Encapsulating PtCl2(4,4′- dimethyl-2,2′-bipyridine)

Shota Tanaka et al.

CHEMISTRY LETTERS (2017)

Add to Collection

Review Chemistry, Inorganic & Nuclear

Recent advances in the construction and applications of heterometallic macrocycles and cages

Ying-Ying Zhang et al.

COORDINATION CHEMISTRY REVIEWS (2017)

Add to Collection

Review Chemistry, Multidisciplinary

Chiral metallosupramolecular architectures

Li-Jun Chen et al.

CHEMICAL SOCIETY REVIEWS (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Regio- and Enantioselective Photodimerization within the Confined Space of a Homochiral Ruthenium/Palladium Heterometallic Coordination Cage

Jing Guo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Add to Collection

Review Chemistry, Multidisciplinary

Sacrificial electron donor reagents for solar fuel production

Yann Pellegrin et al.

COMPTES RENDUS CHIMIE (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Engineering an iridium-containing metal-organic molecular capsule for induced-fit geometrical conversion and dual catalysis

Xuezhao Li et al.

CHEMICAL COMMUNICATIONS (2016)

Add to Collection

Review Chemistry, Multidisciplinary

Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides

David Schilter et al.

CHEMICAL REVIEWS (2016)

Add to Collection

Review Chemistry, Multidisciplinary

Synthesis of Diiron(I) Dithiolato Carbonyl Complexes

Yulong Li et al.

CHEMICAL REVIEWS (2016)

Add to Collection

Review Chemistry, Multidisciplinary

Organic Photoredox Catalysis

Nathan A. Romero et al.

CHEMICAL REVIEWS (2016)

Add to Collection

Review Chemistry, Multidisciplinary

Stabilization of reactive species by supramolecular encapsulation

Albano Galan et al.

CHEMICAL SOCIETY REVIEWS (2016)

Add to Collection

Review Chemistry, Multidisciplinary

Cooperative photoredox catalysis

Xianjun Lang et al.

CHEMICAL SOCIETY REVIEWS (2016)

Add to Collection

Article Chemistry, Multidisciplinary

Controlled Orthogonal Self-Assembly of Heterometal-Decorated Coordination Cages

Guoliang Liu et al.

CHEMISTRY-A EUROPEAN JOURNAL (2016)

Add to Collection

Article Chemistry, Multidisciplinary

Redox-Active M8L6 Cubic Hosts with Tetraphenylethylene Faces Encapsulate Organic Dyes for Light-Driven H2 Production

Linlin Yang et al.

CHEMISTRY-A EUROPEAN JOURNAL (2016)

Add to Collection

Article Chemistry, Multidisciplinary

Supramolecular Photoinduced Electron Transfer between a Redox-Active Hexanuclear Metal-Organic Cylinder and an Encapsulated Ruthenium(II) Complex

Lu Yang et al.

CHEMISTRY-A EUROPEAN JOURNAL (2016)

Add to Collection

Article Chemistry, Organic

A Hantzsch Amido Dihydropyridine as a Transfer Hydrogenation Reagent for α,β-Unsaturated Ketones

Scott A. Van Arman et al.

JOURNAL OF ORGANIC CHEMISTRY (2016)

Add to Collection

Article Chemistry, Organic

Photoredox Catalysis in Organic Chemistry

Megan H. Shaw et al.

JOURNAL OF ORGANIC CHEMISTRY (2016)

Add to Collection

Article Chemistry, Multidisciplinary

A supramolecular ruthenium macrocycle with high catalytic activity for water oxidation that mechanistically mimics photosystem II

Marcus Schulze et al.

NATURE CHEMISTRY (2016)

Add to Collection

Article Multidisciplinary Sciences

A metal-organic cage incorporating multiple light harvesting and catalytic centres for photochemical hydrogen production

Sha Chen et al.

NATURE COMMUNICATIONS (2016)

Add to Collection

Article Chemistry, Physical

Size-Selective Molecular Flasks

Matthias Otte

ACS CATALYSIS (2016)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Metal-organic redox vehicles to encapsulate organic dyes for photocatalytic protons and carbon dioxide reduction

Hao Yu et al.

INORGANIC CHEMISTRY FRONTIERS (2016)

Add to Collection

Review Chemistry, Multidisciplinary

Highly Efficient Bioinspired Molecular Ru Water Oxidation Catalysts with Negatively Charged Backbone Ligands

Lele Duan et al.

ACCOUNTS OF CHEMICAL RESEARCH (2015)

Add to Collection

Article Chemistry, Multidisciplinary

Beyond Molecules: Mesoporous Supramolecular Frameworks Self-Assembled from Coordination Cages and Inorganic Anions

Dong Luo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Add to Collection

Article Chemistry, Multidisciplinary

A highly reducing metal-free photoredox catalyst: design and application in radical dehalogenations

Emre H. Discekici et al.

CHEMICAL COMMUNICATIONS (2015)

Add to Collection

Review Chemistry, Multidisciplinary

Supramolecular Catalysis in Metal-Ligand Cluster Hosts

Casey J. Brown et al.

CHEMICAL REVIEWS (2015)

Add to Collection

Review Chemistry, Multidisciplinary

Applications of Supramolecular Anion Recognition

Nathalie Busschaert et al.

CHEMICAL REVIEWS (2015)

Add to Collection

Review Chemistry, Multidisciplinary

Recent Developments in the Preparation and Chemistry of Metallacycles and Metallacages via Coordination

Timothy R. Cook et al.

CHEMICAL REVIEWS (2015)

Add to Collection

Review Chemistry, Multidisciplinary

Aggregation-Induced Emission: Together We Shine, United We Soar!

Ju Mei et al.

CHEMICAL REVIEWS (2015)

Add to Collection

Review Chemistry, Multidisciplinary

Transition metal catalysis in confined spaces

Stefan H. A. M. Leenders et al.

CHEMICAL SOCIETY REVIEWS (2015)

Add to Collection

Article Chemistry, Multidisciplinary

Efficient Light-Driven Water Oxidation Catalysis by Dinuclear Ruthenium Complexes

Serena Berardi et al.

CHEMSUSCHEM (2015)

Add to Collection

Review Chemistry, Inorganic & Nuclear

Photo-induced redox catalysis for proton reduction to hydrogen with homogeneous molecular systems using rhodium-based catalysts

Thibaut Stoll et al.

COORDINATION CHEMISTRY REVIEWS (2015)

Add to Collection

Article Electrochemistry

Electrochemical-driven water reduction catalyzed by a water soluble cobalt(III) complex with Schiff base ligand

Ting Fang et al.

ELECTROCHIMICA ACTA (2015)

Add to Collection

Article Chemistry, Multidisciplinary

Supramolecular Ga4L612- Cage Photosensitizes 1,3-Rearrangement of Encapsulated Guest via Photoinduced Electron Transfer

Derek M. Dalton et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Add to Collection

Article Chemistry, Multidisciplinary

A Metal-Organic Tetrahedron as a Redox Vehicle to Encapsulate Organic Dyes for Photocatalytic Proton Reduction

Xu Jing et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Add to Collection

Article Chemistry, Multidisciplinary

Combined biomass valorization and hydrogen production in a photoelectrochemical cell

Hyun Gil Cha et al.

NATURE CHEMISTRY (2015)

Add to Collection

Review Chemistry, Multidisciplinary

Controllable Coordination-Driven Self-Assembly: From Discrete Metallocages to Infinite Cage-Based Frameworks

Lian Chen et al.

ACCOUNTS OF CHEMICAL RESEARCH (2015)

Add to Collection

Review Chemistry, Multidisciplinary

Biomedical Applications of Supramolecular Systems Based on Host-Guest Interactions

Xing Ma et al.

CHEMICAL REVIEWS (2015)

Add to Collection

Review Chemistry, Multidisciplinary

Porous Metal-Organic Frameworks for Heterogeneous Biomimetic Catalysis

Min Zhao et al.

ACCOUNTS OF CHEMICAL RESEARCH (2014)

Add to Collection

Review Chemistry, Multidisciplinary

Aggregation-Induced Emission: The Whole Is More Brilliant than the Parts

Ju Mei et al.

ADVANCED MATERIALS (2014)

Add to Collection

Review Chemistry, Multidisciplinary

Review: A History of Cyclodextrins

Gregorio Crini

CHEMICAL REVIEWS (2014)

Add to Collection

Review Chemistry, Multidisciplinary

Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation

Markus D. Karkas et al.

CHEMICAL REVIEWS (2014)

Add to Collection

Review Chemistry, Multidisciplinary

Molecular artificial photosynthesis

Serena Berardi et al.

CHEMICAL SOCIETY REVIEWS (2014)

Add to Collection

Article Chemistry, Multidisciplinary

Light-Induced Proton-Coupled Electron Transfer Inside a Nanocage

Rahul Gera et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Add to Collection

Article Multidisciplinary Sciences

Strong, lightweight, and recoverable three-dimensional ceramic nanolattices

Lucas R. Meza et al.

SCIENCE (2014)

Add to Collection

Article Microbiology

Localized electron transfer rates and microelectrode-based enrichment of microbial communities within a phototrophic microbial mat

Jerome T. Babauta et al.

FRONTIERS IN MICROBIOLOGY (2014)

Add to Collection

Article Chemistry, Multidisciplinary

A photoactive basket-like metal-organic tetragon worked as an enzymatic molecular flask for light driven H2 production

Cheng He et al.

CHEMICAL COMMUNICATIONS (2013)

Add to Collection

Review Chemistry, Multidisciplinary

Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation

Aaron M. Appel et al.

CHEMICAL REVIEWS (2013)

Add to Collection

Review Chemistry, Multidisciplinary

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

Christopher K. Prier et al.

CHEMICAL REVIEWS (2013)

Add to Collection

Review Chemistry, Multidisciplinary

Building on architectural principles for three-dimensional metallosupramolecular construction

Maarten M. J. Smulders et al.

CHEMICAL SOCIETY REVIEWS (2013)

Add to Collection

Article Chemistry, Multidisciplinary

Technical and economic feasibility of centralized facilities for solar hydrogen production via photocatalysis and photoelectrochemistry

Blaise A. Pinaud et al.

ENERGY & ENVIRONMENTAL SCIENCE (2013)

Add to Collection

Article Chemistry, Inorganic & Nuclear

In Situ Construction of a Coordination Zirconocene Tetrahedron

Guoliang Liu et al.

INORGANIC CHEMISTRY (2013)

Add to Collection

Article Chemistry, Physical

Visible light-driven water oxidation catalyzed by mononuclear ruthenium complexes

Lei Wang et al.

JOURNAL OF CATALYSIS (2013)

Add to Collection

Article Chemistry, Multidisciplinary

Unusual Photoreaction of Triquinacene within Self-Assembled Hosts

Takashi Murase et al.

CHEMISTRY-AN ASIAN JOURNAL (2012)

Add to Collection

Article Chemistry, Multidisciplinary

Oxygen evolution from water oxidation on molecular catalysts confined in the nanocages of mesoporous silicas

Bo Li et al.

ENERGY & ENVIRONMENTAL SCIENCE (2012)

Add to Collection

Review Chemistry, Physical

Polyoxometalate-based molecular/nano composites: Advances in environmental remediation by photocatalysis and biomimetic approaches to solar energy conversion

Radhakrishnan Sivakumar et al.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS (2012)

Add to Collection

Article Chemistry, Multidisciplinary

Dihydrophenanthridine: A New and Easily Regenerable NAD(P)H Model for Biomimetic Asymmetric Hydrogenation

Qing-An Chen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Add to Collection

Article Chemistry, Multidisciplinary

A molecular ruthenium catalyst with water-oxidation activity comparable to that of photosystem II

Lele Duan et al.

NATURE CHEMISTRY (2012)

Add to Collection

Article Multidisciplinary Sciences

Photocatalytic CO2 reduction with high turnover frequency and selectivity of formic acid formation using Ru(II) multinuclear complexes

Yusuke Tamaki et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2012)

Add to Collection

Review Chemistry, Multidisciplinary

Enzyme Mimics Based Upon Supramolecular Coordination Chemistry

Michael J. Wiester et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

Add to Collection

Article Chemistry, Multidisciplinary

Structural Modifications of Mononuclear Ruthenium Complexes: A Combined Experimental and Theoretical Study on the Kinetics of Ruthenium-Catalyzed Water Oxidation

Lianpeng Tong et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

Add to Collection

Article Chemistry, Multidisciplinary

Highly Efficient Oxidation of Water by a Molecular Catalyst Immobilized on Carbon Nanotubes

Fei Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

Add to Collection

Article Chemistry, Multidisciplinary

Organocatalysis and C-H Activation Meet Radical- and Electron-Transfer Reactions

Armido Studer et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

Add to Collection

Article Chemistry, Multidisciplinary

A Self-Assembled M8L6 Cubic Cage that Selectively Encapsulates Large Aromatic Guests

Wenjing Meng et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

Add to Collection

Article Chemistry, Multidisciplinary

Photo-driven anti-Markovnikov alkyne hydration in self-assembled hollow complexes

Takashi Murase et al.

CHEMICAL COMMUNICATIONS (2011)

Add to Collection

Article Chemistry, Multidisciplinary

Photocatalytic hydrogen production

Thomas S. Teets et al.

CHEMICAL COMMUNICATIONS (2011)

Add to Collection

Review Chemistry, Multidisciplinary

Supramolecular Coordination: Self-Assembly of Finite Two- and Three-Dimensional Ensembles

Rajesh Chakrabarty et al.

CHEMICAL REVIEWS (2011)

Add to Collection

Review Chemistry, Multidisciplinary

Aggregation-induced emission

Yuning Hong et al.

CHEMICAL SOCIETY REVIEWS (2011)

Add to Collection

Review Chemistry, Multidisciplinary

Visible light photoredox catalysis: applications in organic synthesis

Jagan M. R. Narayanam et al.

CHEMICAL SOCIETY REVIEWS (2011)

Add to Collection

Review Multidisciplinary Sciences

Non-CO2 greenhouse gases and climate change

S. A. Montzka et al.

NATURE (2011)

Add to Collection

Article Chemistry, Multidisciplinary

Visible light-driven water oxidation catalyzed by a highly efficient dinuclear ruthenium complex

Yunhua Xu et al.

CHEMICAL COMMUNICATIONS (2010)

Add to Collection

Review Chemistry, Multidisciplinary

Self-assembled monolayers of thiols and dithiols on gold: new challenges for a well-known system

C. Vericat et al.

CHEMICAL SOCIETY REVIEWS (2010)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Integrating proton coupled electron transfer (PCET) and excited states

Christopher J. Gagliardi et al.

COORDINATION CHEMISTRY REVIEWS (2010)

Add to Collection

Review Chemistry, Inorganic & Nuclear

The catalytic oxidation of biomass to new materials focusing on starch, cellulose and lignin

S. R. Collinson et al.

COORDINATION CHEMISTRY REVIEWS (2010)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Homogeneous photocatalytic production of hydrogen from water by a bioinspired [Fe2S2] catalyst with high turnover numbers

Pan Zhang et al.

DALTON TRANSACTIONS (2010)

Add to Collection

Article Chemistry, Multidisciplinary

A Facile Approach toward Multicomponent Supramolecular Structures: Selective Self-Assembly via Charge Separation

Yao-Rong Zheng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

Add to Collection

Review Chemistry, Multidisciplinary

Small molecule mimics of hydrogenases: hydrides and redox

Frederic Gloaguen et al.

CHEMICAL SOCIETY REVIEWS (2009)

Add to Collection

Review Chemistry, Multidisciplinary

Photocatalysis. A multi-faceted concept for green chemistry

Davide Ravelli et al.

CHEMICAL SOCIETY REVIEWS (2009)

Add to Collection

Article Chemistry, Multidisciplinary

Isolated Seven-Coordinate Ru(IV) Dimer Complex with [HOHOH]- Bridging Ligand as an Intermediate for Catalytic Water Oxidation

Lele Duan et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

Add to Collection

Article Multidisciplinary Sciences

Self-assembled biomimetic [2Fe2S]-hydrogenase-based photocatalyst for molecular hydrogen evolution

A. M. Kluwer et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2009)

Add to Collection

Article Chemistry, Multidisciplinary

Highly selective photomediated 1,4-radical addition to o-quinones controlled by a self-assembled cage

Takumi Yamaguchi et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

Add to Collection

Review Chemistry, Multidisciplinary

Reactivity within a confined self-assembled nanospace

Tehila S. Koblenz et al.

CHEMICAL SOCIETY REVIEWS (2008)

Add to Collection

Article Chemistry, Multidisciplinary

Development of an efficient photocatalytic system for CO2 reduction using rhenium(l) complexes based on mechanistic studies

Hiroyuki Takeda et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)

Add to Collection

Article Chemistry, Multidisciplinary

Asymmetric [2+2] olefin cross photoaddition in a self-assembled host with remote chiral auxiliaries

Yuki Nishioka et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)

Add to Collection

Article Multidisciplinary Sciences

Merging photoredox catalysis with organocatalysis: The direct asymmetric alkylation of aldehydes

David A. Nicewicz et al.

SCIENCE (2008)

Add to Collection

Article Chemistry, Applied

Photocatalytic splitting of H2S to produce hydrogen by gas-solid phase reaction

Ma Guijun et al.

CHINESE JOURNAL OF CATALYSIS (2008)

Add to Collection

Article Chemistry, Physical

Hydrogen production from a chemical cycle of H2S splitting

Hui Wang

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2007)

Add to Collection

Article Chemistry, Multidisciplinary

Self-assembly of nanosize coordination cages on Si(100) surfaces

Marco Busi et al.

CHEMISTRY-A EUROPEAN JOURNAL (2007)

Add to Collection

Article Chemistry, Multidisciplinary

Visible light induced catalytic water reduction without an electron relay

Leonard L. Tinker et al.

CHEMISTRY-A EUROPEAN JOURNAL (2007)

Add to Collection

Article Chemistry, Multidisciplinary

The confined cavity of a coordination cage suppresses the photocleavage of alpha-diketones to give cyclization products through kinetically unfavorable pathways

Takahito Furusawa et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2007)

Add to Collection

Review Chemistry, Multidisciplinary

Reversible guest exchange mechanisms in supramolecular host-guest assemblies

Michael D. Pluth et al.

CHEMICAL SOCIETY REVIEWS (2007)

Add to Collection

Article Chemistry, Multidisciplinary

Grafting cavitands on the Si(100) surface

Guglielmo G. Condorelli et al.

LANGMUIR (2006)

Add to Collection

Review Chemistry, Multidisciplinary

Water-splitting chemistry of photosystem II

James P. McEvoy et al.

CHEMICAL REVIEWS (2006)

Add to Collection

Article Chemistry, Multidisciplinary

Room-temperature and solution-state observation of the mixed-valence cation radical dimer of tetrathiafulvalene, [(TTF)2]+•, within a self-assembled

M Yoshizawa et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)

Add to Collection

Review Chemistry, Multidisciplinary

Alfred Werner revisited: The coordination chemistry of anions

K Bowman-James

ACCOUNTS OF CHEMICAL RESEARCH (2005)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Architecture of supramolecular metal complexes for photocatalytic CO2 reduction:: Ruthenium-rhenium bi- and tetranuclear complexes

B Gholamkhass et al.

INORGANIC CHEMISTRY (2005)

Add to Collection

Review Chemistry, Multidisciplinary

Coordination assemblies from a Pd(II)-cornered square complex

M Fujita et al.

ACCOUNTS OF CHEMICAL RESEARCH (2005)

Add to Collection

Review Chemistry, Multidisciplinary

Metallosupramolecular squares:: from structure to function

F Würthner et al.

CHEMICAL SOCIETY REVIEWS (2004)

Add to Collection

Article Chemistry, Multidisciplinary

Alkane oxidation via photochemical excitation of a self-assembled molecular cage

M Yoshizawa et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2004)

Add to Collection

Review Chemistry, Multidisciplinary

Tetrathiafulvalenes, oligoacenenes, and their buckminsterfullerene derivatives: The brick and mortar of organic electronics

M Bendikov et al.

CHEMICAL REVIEWS (2004)

Add to Collection

Article Chemistry, Multidisciplinary

Surface-confined single molecules: Assembly and disassembly of nanosize coordination cages on gold (111)

E Menozzi et al.

CHEMISTRY-A EUROPEAN JOURNAL (2004)

Add to Collection

Article Chemistry, Multidisciplinary

Cavity-directed synthesis within a self-assembled coordination cage: Highly selective [2+2] cross-photodimerization of olefins

M Yoshizawa et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003)

Add to Collection

Article Multidisciplinary Sciences

Photoelectrochemical cells

M Grätzel

NATURE (2001)

Add to Collection

Supramolecular Coordination Cages for Artificial Photosynthesis and Synthetic Photocatalysis

Related references