Journal
CHEMICAL ENGINEERING JOURNAL
Volume 452, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2022.139518
Keywords
Radiative cooling; Aerogel; Thermal emission; Heat resistance; Compression fatigue resistance
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Radiative cooling is an important passive cooling technology that can directly radiate heat to outer space, reducing energy consumption. Researchers have found that silica-alumina nanofibrous aerogels (SAFAs) synthesized by electrospinning can achieve efficient and cost-effective radiative cooling, along with excellent additional properties.
Radiative cooling is a passive cooling technology that radiates heat directly to outer space without any additional energy input and is therefore of great significance in reducing the consumption of energy. However, the radiative cooling in subambient daytime is difficult to implement and usually requires complicated structural designs, such as photonic crystals and metamaterials, which are neither cost-effective nor scalable. Here, we demonstrate that silica-alumina nanofibrous aerogels (SAFAs) synthesized by electrospinning can provide a high solar reflectance of similar to 95 % and a high atmospheric window emissivity of similar to 93 %, owing to the scattering reflection and selective emission of the fiber network in aerogel. During field tests, the SAFAs remain more than 5 C-? below the ambient temperature, theoretically yielding a radiative cooling power of similar to 133.1 W m(-2). Through scalable manufacturing routes, the SAFAs exhibit high compression fatigue resistance, robust fire resistance and excellent thermal insulation. The low cost and high performance of these SAFAs present great potential for large-scale passive radiative cooling applications.
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