Journal
CHEMICAL ENGINEERING JOURNAL
Volume 449, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2022.137875
Keywords
Antifouling; Bioinspired; Polyurethane; Silicone; Self-stratification
Categories
Funding
- National Natural Science Foundation of China [52003082]
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This study presents a bioinspired self-stratifying coating composed of a polyurethane and a bi-silanol-terminated poly(dimethylsiloxane), which demonstrates excellent antifouling ability, self-healing performance, and strong substrate adhesion. The coating exhibits resistance against proteins, bacteria, and diatoms, as well as the ability to heal at room temperature in air and water. It also demonstrates high adhesion strength on various substrates such as ceramic, steel, glass, and wood.
Antifouling ability and substrate adhesion are typical trade-offs seen for a silicone coating. Furthermore, the self- healable inability limits their duration. This study reports a bioinspired self-stratifying coating composed of a polyurethane with dopamine and silane pedant groups and a bi-silanol-terminated poly(dimethylsiloxane) with fluorocarbon and poly(ethylene glycol) segments as a reactive amphiphilic polymer (RAP). During coating for-mation, the RAP with low surface energy can be enriched on the surface due to the self-stratifying effects, whereas the bioinspired dopamine and silane groups provide the coating with strong substrate adhesion. Besides, the multiple hydrogen bonds formed between the urethane linkages and the dopamine groups allow the coating to heal. Our study indicates such a polyurethane-based coating has excellent antifouling ability against proteins, bacteria, and diatoms, good self-healing performance at room temperature in air and water, as well as high adhesion strength on various substrates such as ceramic, steel, glass, and wood. This study provides a promising and universal strategy for the simultaneous realization of antifouling, self-healing, and strong substrate adhesion. The coatings could meet the needs of applications in marine antifouling, biomedical instruments, and other fields
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