Journal
CHEMICAL COMMUNICATIONS
Volume 59, Issue 9, Pages 1205-1208Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc05840e
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A visible-light-induced radical/radical cross-coupling reaction of quaternary ammonium salts and Hantzschs via C-N and C-C bond cleavage is reported, leading to the formation of 1,2-diphenylethanes. The synthetic approach provides a moderate to good yield and offers a method for constructing C(sp(3))-C(sp(3)) bonds.
Radical/radical cross-coupling remains challenging due to diffusion control issues. Herein, we report a visible-light-induced radical/radical cross-coupling reaction of quaternary ammonium salts and Hantzschs via C-N and C-C bond cleavage. The current synthetic approach furnishes 1,2-diphenylethanes in moderate to good yields and provides a method for the construction of the C(sp(3))-C(sp(3)) bond.
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