Journal
CHEMICAL COMMUNICATIONS
Volume 59, Issue 4, Pages 426-429Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc04394g
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Directing groups are crucial for controlling the selectivity of C-H bond activation. In this study, we show that the nature of the directing group (ketone, ester, or amide) influences the C-H activation process for iron, leading to distinct cis- and trans-isomers of the corresponding iron hydrides.
Directing groups play an important role in controlling the selectivity of C-H bond activation. Here we demonstrate that for iron, the nature of the directing group (e.g., ketone, ester, or amide) influences the C-H activation process. In this study the C-H bond activation step either occurs with or without the assistance of the directing group resulting in distinct cis- and trans-isomers of the corresponding iron hydride.
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