Journal
CHEMICAL COMMUNICATIONS
Volume 59, Issue 16, Pages 2255-2258Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3cc00036b
Keywords
-
Categories
Ask authors/readers for more resources
This study presents a transition metal-free method for the efficient and controlled reduction of isocyanates to formamide derivatives using pinacolborane as the hydrogenating agent and a magnesium methyl complex with a bis(phosphino)carbazole ligand as the catalyst. A wide range of substrates undergo selective hydroboration, yielding exclusively N-boryl formamides.
This work describes a transition metal-free methodology involving an efficient and controlled reduction of isocyanates to only formamide derivatives using pinacolborane (HBpin) as the hydrogenating agent and a bis(phosphino)carbazole ligand stabilized magnesium methyl complex (1) as the catalyst. A large number of substrates undergo selective hydroboration and give exclusively N-boryl formamides.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available