4.7 Article

Prussian blue/RGO with less coordinated water as superior cathode material for sodium-ion batteries

Journal

CHEMICAL COMMUNICATIONS
Volume 59, Issue 2, Pages 211-214

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc04702k

Keywords

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Funding

  1. Natural Science Foundation of China [21336003, 21073120]
  2. Major Basic Research Program of China [2014CB239700]
  3. Science and Technology Commission of Shanghai Municipality [14DZ2250800]
  4. Shanghai Natural Science Foundation [15ZR1422300]

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A nano-composite material with improved performance was developed by modifying the structure of Prussian blue and utilizing electron exchange between graphene oxide and PB. It exhibited excellent properties as a cathode in sodium-ion batteries.
A micro-cubic Prussian blue (PB) with less coordinated water is first developed by electron exchange between graphene oxide and PB. The obtained reduced graphene oxide-PB composite exhibited increased redox reactions of the Fe sites and delivered ultrahigh specific capacity of 163.3 mA h g(-1) (30 mA g(-1)) as well as excellent cycle stability as a cathode in sodium-ion batteries.

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