Journal
CHEMICAL COMMUNICATIONS
Volume 59, Issue 10, Pages 1297-1300Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc06708k
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N-Sulfonylthioimidate is converted to ketenimine under basic conditions. The reaction with vinyl/aryl azides induces dipolar cycloaddition to form 5-amino-1-vinyl/aryl-1,2,3-triazoles. The method boasts high efficiency, diverse product structures, favorable yields, and applicability to gram-scale operations.
N-Sulfonylthioimidate was converted to ketenimine under basic conditions. The reaction with vinyl/aryl azides was induced to cause dipolar cycloaddition to form 5-amino-1-vinyl/aryl-1,2,3-triazoles. The advantages of this method are high efficiency, structural diversity of products favorable yields and applicability to gram-scale operations.
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