Preparation of novel KAlSiO4: Ce3+ broadband cyan-emitting phosphors via partial cation substitution for applications in white-light LEDs

Broadband cyan-emitting phosphors with strong absorption between 300 and 400 nm are ideal replacements for traditional blue and green phosphors used in commercial light-emitting diodes (LEDs). In this paper, a series of K1-xAlSiO4: xCe(3+)(x = 0.02-0.06) broadband cyan phosphors were prepared using the traditional hightemperature solid state method and the cation un-equivalent substitution strategy. It was found that the KAl-SiO4 matrix has a monoclinic structure with high symmetry. The experimental and theoretical optical band gaps of the host were 5.6 eV and 4.86 eV, respectively. After doping with Ce3+, strong absorption was observed in the near ultraviolet region. The optimum Ce3+ doping concentration in the host was 0.04 as indicated by the strongest observed emission intensity. The full width at half maximum of the emission spectra of the series of samples are all greater than 120 nm and covered the blue and green wavelength ranges (370-600 nm). The luminous intensity of the K0.96AlSiO4: 0.04Ce(3+)phosphor at 150.C was 91.1% of that at room temperature, and the Gaussian peak of the emission spectrum slightly broadened. These results were also combination with theoretical DFT calculations. It was found that the phosphor had very good thermal stability and rigidity. The phosphor was also mixed with a commercial red phosphor, interfaced with a UV chip and packaged into an LED. This LED was characterized and had a color rendering index greater than 90 across a broad range of drive currents. This work highlights the utility of the fabricated phosphor as means of simplifying white-light LED fabrication.

Automated summary

In this paper, a series of broadband cyan phosphors were prepared and characterized. The K0.96AlSiO4:0.04Ce(3+) phosphor showed the highest emission intensity and wide emission spectrum suitable for commercial LED applications.