4.7 Article

Dual composite architectonics: Fracture toughness and self-healing of ZrB2-SiC-TaB2 based UHTC

Journal

CERAMICS INTERNATIONAL
Volume 49, Issue 9, Pages 13648-13656

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2022.12.241

Keywords

Fracture toughness; Self-healing; Dual composite; Functional ceramics; Residual strength

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This study examines the impact of structural architecture on the fracture toughness and self-healing ability of ZrB2-SiC-TaB2 composites. It is found that the dual composite architecture enhances the fracture toughness through crack arrest and elastic microstress fields. Additionally, the SiC component enables the composites to self-heal surface defects at high temperatures, thereby preventing crack initiation. The analysis of residual strength after self-healing helps determine the optimal matrix-inclusion ratio for minimizing reliability loss.
This study explores the effect of structural architecture of ZrB2-SiC-TaB2 composites on their fracture toughness and ability to self-heal operational surface defects. It is shown that the dual composite architecture provides a synergistic combination of several effects enhancing the fracture toughness of the material: crack arrest in the developed system of polymodal interphase boundaries, and formation of elastic microstress fields. In addition, SiC that is rapidly oxidized and forms an easily fusible borosilicate layer endows MeBx-based dual composites with the ability to self-heal surface defects when operating at temperatures above 1000 degrees C in an oxygen -containing environment, preventing crack initiation from surface stress concentrators. The analysis of the re-sidual strength after self-healing in comparison with the initial data of the studied materials allowed the optimal matrix-inclusion ratio, minimizing the loss of reliability.

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