Journal
CATALYSIS LETTERS
Volume -, Issue -, Pages -Publisher
SPRINGER
DOI: 10.1007/s10562-023-04274-6
Keywords
Vanadium-doped phosphomolybdic acids; beta-Citronellal; Acetals; Terpenes aldehydes
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In this study, catalysts with the general formula H3+nPMo12-nVnO40 (n = 0, 1, 2 and 3) were used to replace molybdenum atoms with vanadium, and these catalysts were applied in the acetalization reaction of alkyl alcohols with terpene aldehyde. The focus was on evaluating the impact of vanadium load on the catalytic activity of phosphomolybdic acids and linking this effect with their structural properties. The results showed that the vanadium monosubstituted phosphomolybdic acid had the highest activity and selectivity in the formation of beta-citronellyl acetal. The effects of various reaction variables on conversion and selectivity were also investigated.
In this work, vanadium replaced molybdenum atoms generating catalysts with general formulae H3+nPMo12-nVnO40 (n = 0,1, 2 and 3), which were used in the acetalization of alkyl alcohols with terpene aldehyde (beta-citronellal and methyl alcohol were model substrates). The initial focus was evaluating how the vanadium load impact the catalytic activity of phosphomolybdic acids and trying to link this effect with their structural properties. A comparison of performance achieved by the catalysts revealed that among phosphomolybdic acids (i.e., with V-1, V-2, and V-3 atoms/per anion), the vanadium monosubstituted phosphomolybdic acid was the most active and selective toward the formation of beta-citronellyl acetal. The effects of main reaction variables such as time, temperature, catalyst load, type of alcohol, and vanadium load on conversion and selectivity of the reactions were investigated. Remarkably, while in methyl alcohol, only acetal was formed, in the presence of other alkyl alcohols terpene ethers (geranyl and beta-citronellyl) were also obtained. Their highest activity of H4PMo11VO40 was attributed to the greatest Bronsted acidity strength, as demonstrated by the acidity measurements and infrared spectroscopy analysis. This catalyst has advantages over traditional liquid mineral acid catalysts and provides an alternative route to synthesize acetal and terpene ethers. [GRAPHICS]
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