4.5 Article

New Process of 2-Nitrotoluene into 2-Methylaniline by Transfer Hydrogenation with Methanol over X Zeolite Catalyst

Journal

CATALYSIS LETTERS
Volume 146, Issue 1, Pages 174-179

Publisher

SPRINGER
DOI: 10.1007/s10562-015-1633-1

Keywords

Transfer hydrogenation; Methanol; X zeolite; 2-Nitrotoluene; 2-Methylaniline

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A new transfer hydrogenation of 2-nitrotoluene with methanol to 2-methylaniline was successfully implemented. The transfer hydrogenation of 2-nitrotoluene with methanol showed much faster rate than its hydrogenation with hydrogen over X zeolites. Based on the reaction results over different modified X zeolites and activated carbon, a radical mechanism was proposed. [GRAPHICS] .

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