Journal
CATALYSIS COMMUNICATIONS
Volume 65, Issue -, Pages 91-95Publisher
ELSEVIER
DOI: 10.1016/j.catcom.2015.02.017
Keywords
Metal-organic frameworks; Palladium nanoparticles; Suzuki coupling; Titanium; Heterogeneous catalyst
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Funding
- National Research Foundation of Korea (NRF) - Korean Government (MEST) [2013005862]
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Pd nanoparticles were deposited successfully on a porous metal-organic framework NH2-MIL-125, and characterized by powder X-ray diffraction, thermogravimetric analysis, N-2 adsorption-desorption isotherms, X-ray photoelectron spectroscopy, and field emission transmission electron microscopy. The as-synthesized NH2-MIL-125-supported palladium nanopartides exhibited excellent heterogeneous catalytic performance towards Suzuki cross coupling between the aryl chlorides and arylboronic acids. The catalyst could be reused at least four times under the optimized conditions with only a minor decrease in catalytic activity. The Sheldon test confirmed the heterogeneity of the catalyst. (C) 2015 Elsevier B.V. All rights reserved.
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