Journal
CATALYSIS COMMUNICATIONS
Volume 58, Issue -, Pages 141-148Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2014.09.006
Keywords
Post-synthetic modification; IRMOF-3; Cu(II); Heterogeneous catalysis; O-arylation; Shape selectivity
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Funding
- CSIR, New Delhi [01(2542)/11/EMR-II]
- Council of Scientific and Industrial Research (CSIR), New Delhi
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A highly porous Zn-based iso-reticular metal-organic framework (IRMOF-3) has been selected for covalent modification. Pyridine-2-aldehyde has been used to decorate the free amine group of IRMOF-3 in the porous matrix. Schiff base moiety thus generated has been availed to anchor copper(II) ions to prepare the desired catalyst that catalyzes O-arylation reactions heterogeneously under mild reaction conditions. Porous catalyst demonstrates size selectivity in products when various substrates undergo O-arylation with alpha and beta-naphthol. (C) 2014 Elsevier BM. All rights reserved.
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