Diverse Carbonates in Exoplanet Oceans Promote the Carbon Cycle

Carbonate precipitation in oceans is essential for the carbonate-silicate cycle (inorganic carbon cycle) to maintain temperate climates. By considering the thermodynamics of carbonate chemistry, we demonstrate that the ocean pH decreases by approximately 0.5 for a factor of 10 increase in the atmospheric carbon dioxide content. The upper and lower limits of ocean pH are within 1-4 of each other, where the upper limit is buffered by carbonate precipitation and defines the ocean pH when the carbon cycle operates. If the carbonate compensation depth (CCD) resides above the ocean floor, then carbonate precipitation and the carbon cycle cease to operate. The CCD is deep (>40 km) for high ocean temperature and high atmospheric carbon dioxide content. Key divalent carbonates of magnesium, calcium and iron produce an increasingly wider parameter space of deep CCDs, suggesting that chemical diversity promotes the carbon cycle. The search for life from exoplanets will benefit by including chemically more diverse targets than Earth twins.

Automated summary

Carbonate precipitation in oceans is crucial for maintaining the inorganic carbon cycle and temperate climates. The ocean pH decreases by approximately 0.5 for every tenfold increase in atmospheric carbon dioxide. The upper limit of ocean pH, buffered by carbonate precipitation, defines the pH when the carbon cycle operates, while if the carbonate compensation depth (CCD) resides above the ocean floor, the carbon cycle ceases to operate.