Journal
CATALYSIS COMMUNICATIONS
Volume 62, Issue -, Pages 95-99Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2015.01.012
Keywords
Rhodium; Asymmetric catalysis; Transfer hydrogenation; Ketone; Enantioselectivity; Reduction
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Funding
- Agence Nationale de la Recherche [ANR-11-BS07-017-02]
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A new Rh(III) complex containing the TsDPEN ligand and an eta(6)-arene connected through a carbon tether is reported. The asymmetric transfer hydrogenation of a series of ketones catalyzed by this complex using the formic acid/triethylamine system provided the corresponding alcohols with complete conversions and a high level of enantioselectivity. (C) 2015 Elsevier B.V. All rights reserved.
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