Journal
APPLIED SURFACE SCIENCE
Volume 609, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.apsusc.2022.155218
Keywords
Schottky barrier; Ballistic Electron Emission Spectroscopy (BEES); Gold (Au); Germanium (Ge); Metal-semiconductor interface
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We propose a phase-space ab-initio formalism to calculate the current-voltage relationship of Ballistic Electron Emission Spectroscopy in a metal-semiconductor interface. The injection of electrons or holes under direct or reverse bias is studied. This research is important for determining the key technological characteristic of metal-semiconductor rectifying interfaces - the Schottky barrier.
We develop a phase-space ab-initio formalism to compute Ballistic Electron Emission Spectroscopy current- voltage I(V)'s in a metal-semiconductor interface. We consider injection of electrons into the conduction band for direct bias (V > 0) and injection of holes into the valence band or injection of secondary Auger electrons into the conduction band for reverse bias (V < 0). Here, an ab-initio description of the semiconductor inversion layer (spanning hundreds of Angstroms) is needed. Such formalism is helpful to get parameter-free best-fit values for the Schottky barrier, a key technological characteristic for metal-semiconductor rectifying interfaces. We have applied the theory to characterize the Au/Ge(001) interface; a double barrier is found for electrons injected into the conduction band - either directly or created by the Auger process - while only a single barrier has been identified for holes injected into the valence band.
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