Origin of interfacial charges of Al2O3/Si and Al2O3/GaN heterogeneous heterostructures

Al2O3 is a broadly employed dielectric and significant interfacial charges occur at Al2O3/semiconductor interfaces. However, the charge origin is often unclear that severely impacts device engineering and design. Al2O3/Si and Al2O3/GaN are two of the most common heterogeneous heterostructures (H(2)s) for many crucial devices including GaN transistors and Si solar cells. While negative charges are extensively observed in Al2O3/Si, positive charges exist in Al2O3/GaN, both of which are not well understood. In this study, we performed in-depth interfacial studies of the Al2O3/Si and Al2O3/GaN H(2)s to clarify the origin of the interfacial charges. Stoichiometry deviations were found at the interfaces of the two H(2)s where Al surpasses O for (Al2O3)/GaN, whereas O dominates at the Al2O3/Si interface. Therefore, we propose that the different interfacial charges are caused by nonstoichiometry atomic ratios of Al2O3 at the interface. The study indicates the important role of the semiconductor surface on the device performance, provide a deep understanding on the origin of interfacial charges at the insulator-semiconductor interfaces.

Automated summary

The origin of interfacial charges in Al2O3/Si and Al2O3/GaN was studied, and it was found that the chemical stoichiometry deviations at the interfaces caused the different interfacial charges.