4.6 Article

Tunneling injection to trap-limited space-charge conduction for metal-insulator junction

Journal

APPLIED PHYSICS LETTERS
Volume 121, Issue 19, Pages -

Publisher

AIP Publishing
DOI: 10.1063/5.0124748

Keywords

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Funding

  1. ASTAR AME IRG [A2083c0057]
  2. SUTD Start-Up Research Grant [SRG SCI 2021 163]

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This paper investigates the current transport in a biased trap-filled insulator, analyzing the effects of Schottky barrier at the metal-insulator junction and developing a correct IV characteristics calculation model. The findings highlight the interplay between various transport mechanisms, providing important insights for studying current transport in novel insulators.
For a biased trap-filled insulator, the current transport is governed by the physics of charge injection from the metallic electrode and also the trap-limited space-charge conduction in the insulator. With a Schottky barrier at the interface of the metal-insulator junction, charge tunneling injection from a metal into the trap-filled insulator is different from an Ohmic contact. At sufficiently large amount of charge injection at high voltages, the charge transport becomes the trap-limited space-charge conduction. In this paper, we develop a consistent model to calculate the correct IV characteristics up to a breakdown field strength of 1 V/nm. Using this model, we analyze the transport characteristic of three different metal-insulator junctions (ITO/PPV, Al/h-BN, and Al/ZrO2) and identify the conduction mechanisms over a wide range of the applied voltage, insulator's thickness, and properties of the traps. Our findings report the interplay between various transport mechanisms, which is useful to characterize the correct current transport for novel insulators such as organic semiconductors, 2D insulators, and metal-oxide electronics.

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