☆ 4.8 Article

Highly active Pt/In2O3-ZrO2 catalyst for CO2 hydrogenation to methanol with enhanced CO tolerance: The effects of ZrO2

APPLIED CATALYSIS B-ENVIRONMENTAL (2023)

Related references

Note: Only part of the references are listed.

Article Chemistry, Applied

Synergistic effect of the metal-support interaction and interfacial oxygen vacancy for CO2 hydrogenation to methanol over Ni/In2O3 catalyst: A theoretical study

Chenyang Shen et al.

Summary: Nickel catalyst supported by indium oxide has been proven to be highly active for CO2 hydrogenation to methanol, with the RWGS pathway being the most theoretically favored. It has been demonstrated that the interfacial oxygen vacancy serves as an active site for promoting CO2 hydrogenation by facilitating charge transfer between nickel species and indium oxide.

JOURNAL OF ENERGY CHEMISTRY (2022)

Add to Collection

Article Chemistry, Physical

Insights into the alloy-support synergistic effects for the CO2 hydrogenation towards methanol on oxide-supported Ni5Ga3 catalysts: An experimental and DFT study

Leticia F. Rasteiro et al.

Summary: Supported Ni-Ga alloys have shown potential as catalysts for converting CO2 into methanol, but their performance depends on the optimization of alloy-support effects, which is still unclear. This study investigated the influence of alloy-support synergy on the catalytic performance of Ni5Ga3 supported on different materials, revealing that Ni5Ga3/ZrO2 exhibited the best catalytic activity and proposed a reaction mechanism for this catalyst.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Add to Collection

Article Chemistry, Physical

Atomic Pd-promoted ZnZrOx solid solution catalyst for CO2 hydrogenation to methanol

Kyungho Lee et al.

Summary: In this study, an atomic Pd-promoted ZnZrOx solid solution catalyst (Pd-ZnZrOx) was designed and synthesized, showing excellent activity and stability in the conversion of CO2 to methanol.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Add to Collection

Article Chemistry, Physical

CO2 hydrogenation to methanol on tungsten-doped Cu/CeO2 catalysts

Yong Yan et al.

Summary: The catalytic hydrogenation of CO2 to methanol can be improved by doping tungsten into CeO2, resulting in a Cu/CeW0.25Ox catalyst with enhanced activity and selectivity. Experimental investigation reveals that this promotion effect is attributed to the reduction of Ce4+ to Ce3+ by W-doping, the suppression of oxygen vacancy formation on CeO2, and the activation of the formate pathway for CO2 hydrogenation. This catalyst design strategy differs from conventional CeO2-supported catalysts.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

Add to Collection

Article Chemistry, Physical

The feasibility study of the indium oxide supported silver catalyst for selective hydrogenation of CO2 to methanol

Kaihang Sun et al.

Summary: The feasibility of indium oxide supported silver catalyst for CO2 hydrogenation to methanol was investigated using density functional theoretical (DFT) study and experimental investigation. The study revealed the intense Ag-In2O3 interaction which positively charged the silver species and facilitated the activation and dissociation of carbon dioxide. The experimental study confirmed the high methanol selectivity of the Ag/In2O3 catalyst and demonstrated its potential as an efficient catalyst for CO2 hydrogenation.

GREEN ENERGY & ENVIRONMENT (2022)

Add to Collection

Article Chemistry, Applied

Highly dispersed Cd cluster supported on TiO2 as an efficient catalyst for CO2 hydrogenation to methanol

Jijie Wang et al.

Summary: In this study, a new Cd/TiO2 catalyst with high selectivity for the hydrogenation of CO2 to methanol was reported. Experimental and computational studies revealed that the unique electronic properties exhibited by Cd clusters played a key role at the interfacial catalytic sites.

CHINESE JOURNAL OF CATALYSIS (2022)

Add to Collection

Article Chemistry, Applied

CO2 hydrogenation to methanol at high reaction temperatures over In2O3/ ZrO2 catalysts: Influence of calcination temperatures of ZrO2 support

Thanapha Numpilai et al.

Summary: The calcination temperature of ZrO2 support plays a crucial role in the crystal structure and reducibility of In2O3, as well as in the formation of methane and methanol. Different calcination temperatures of ZrO2 support significantly affect the yield of methane and methanol.

CATALYSIS TODAY (2021)

Add to Collection

Article Chemistry, Applied

CO2 hydrogenation to methanol over Rh/In2O3 catalyst

Jing Wang et al.

Summary: Highly dispersed Rh/In2O3 catalyst prepared by deposition-precipitation method shows excellent activity and selectivity for CO2 hydrogenation to methanol, promoting the reaction even at lower temperatures.

CATALYSIS TODAY (2021)

Add to Collection

Article Chemistry, Physical

Atomically dispersed Ptn+species as highly active sites in Pt/In2O3 catalysts for methanol synthesis from CO2 hydrogenation

Zhe Han et al.

Summary: The methanol selectivity of In2O3 catalyst can be significantly enhanced by introducing a small amount of Pt, leading to a higher efficiency in the process of CO2 hydrogenation to methanol.

JOURNAL OF CATALYSIS (2021)

Add to Collection

Article Chemistry, Physical

Relations between Surface Oxygen Vacancies and Activity of Methanol Formation from CO2 Hydrogenation over In2O3 Surfaces

Ang Cao et al.

Summary: The study investigated the catalytic activity of In2O3 (111) and In2O3 (110) in methanol synthesis, finding a relationship between the number of reduced surface In layers and catalytic activity. By adding a ZrO2 support, the activity of In2O3 catalyst in methanol formation can be optimized.

ACS CATALYSIS (2021)

Add to Collection

Article Chemistry, Physical

Impact of hybrid CO2-CO feeds on methanol synthesis over In2O3-based catalysts

Thaylan P. Araujo et al.

Summary: This study evaluated the sensitivity of In2O3 catalysts to CO, finding a decrease in methanol productivity for most catalysts except one. Controlled formation of oxygen vacancies and resistance to sintering were identified as key factors for activation, while a combination of CO/H2O-induced sintering and CO inhibition caused performance loss. Assessment with mixed CO2-CO feeds is crucial for designing industrially viable catalysts for sustainable methanol production.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Experimental and theoretical studies of CO2 hydrogenation to methanol on Ru/In2O3

Qinglei Wu et al.

Summary: In this study, a Ru/In2O3 catalyst with high dispersion and activity was prepared by deposition precipitation method for CO2 hydrogenation to methanol. The Ru loading enhanced the activation ability of hydrogen and CO2, leading to high methanol selectivity and space-time yield. Theoretical analysis showed that the CO-hydrogenation route on Ru/In2O3 was thermodynamically favored for methanol production from CO2.

JOURNAL OF CO2 UTILIZATION (2021)

Add to Collection

Article Chemistry, Physical

Theoretical Study of Selective Hydrogenation of CO2 to Methanol over Pt4/In2O3 Model Catalyst

Kaihang Sun et al.

Summary: Through theoretical calculations, this study reveals the reaction mechanism of methanol synthesis from CO2 hydrogenation on a Pt-4/In2O3 model catalyst, confirming the strong metal-support interaction induced by surface oxygen vacancy. Methanol synthesis primarily proceeds via the CO hydrogenation route, while the formate route and RWGS route are deemed infeasible due to high activation energy barriers.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

Add to Collection

Article Multidisciplinary Sciences

Nanostructure of nickel-promoted indium oxide catalysts drives selectivity in CO2 hydrogenation

Matthias S. Frei et al.

Summary: This study investigates the complex interplay between nanostructure and product selectivity of nickel-promoted In2O3 in CO2 hydrogenation to methanol. The presence of nickel on the oxide surface forms InNi3 patches, which boost methanol production by providing neutral hydrogen species. Ratios of nickel to In content influence the formation of different structures and the production of CO and methane in the reaction.

NATURE COMMUNICATIONS (2021)

Add to Collection

Article Chemistry, Physical

Highly Active Ir/In2O3 Catalysts for Selective Hydrogenation of CO2 to Methanol: Experimental and Theoretical Studiese

Chenyang Shen et al.

Summary: Iridium (Ir) catalysts supported by indium oxide show high activity and selectivity in CO2 hydrogenation to methanol, with higher Ir loading leading to enhanced activity. The intense interaction between Ir and In2O3 on the catalysts results in high dispersion and the Ir-In2O3 interface as the active site for selective hydrogenation of CO2 into methanol.

ACS CATALYSIS (2021)

Add to Collection

Article Chemistry, Physical

Ni-In Synergy in CO2 Hydrogenation to Methanol

Jiadong Zhu et al.

Summary: This study investigates the promotion of Ni on In2O3 and optimization of NiO-In2O3 catalyst for CO2 hydrogenation. Ni facilitates the synthesis of CH3OH by reducing the dissociation barrier of H2, leading to reduced activation energy for CO2 hydrogenation. The interaction between Ni cations and In2O3 at low NiO loading enhances the surface density of oxygen vacancy, promoting the hydrogenation of adsorbed CO2 on O-v.

ACS CATALYSIS (2021)

Add to Collection

Article Chemistry, Physical

A DFT-based microkinetic study on methanol synthesis from CO2 hydrogenation over the In2O3 catalyst

Zhimin Zhou et al.

Summary: In this study, DFT calculations and microkinetic simulations were used to investigate the reaction mechanisms of methanol synthesis on the (111) and (110) surfaces of In2O3 catalyst. It was found that the deoxygenation of CO2 to form CO is slower than methanol formation under typical steady state conditions. Additionally, the rate-controlling step for CO2 hydrogenation to methanol over the (111) surface was identified as homolytic H-2 dissociation, suggesting potential pathways for enhancing CO2 conversion and methanol selectivity.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Recent Advances in Carbon Dioxide Hydrogenation to Methanol via Heterogeneous Catalysis

Xiao Jiang et al.

CHEMICAL REVIEWS (2020)

Add to Collection

Article Chemistry, Physical

A combined experimental and DFT study of H2O effect on In2O3/ZrO2 catalyst for CO2 hydrogenation to methanol

Xiao Jiang et al.

JOURNAL OF CATALYSIS (2020)

Add to Collection

Article Chemistry, Physical

Role of Zirconia in Indium Oxide-Catalyzed CO2 Hydrogenation to Methanol

Matthias S. Frei et al.

ACS CATALYSIS (2020)

Add to Collection

Article Chemistry, Physical

Metal-Organic Framework-Derived Synthesis of Cobalt Indium Catalysts for the Hydrogenation of CO2 to Methanol

Alexey Pustovarenko et al.

ACS CATALYSIS (2020)

Add to Collection

Article Multidisciplinary Sciences

Rationally designed indium oxide catalysts for CO2 hydrogenation to methanol with high activity and selectivity

Shanshan Dang et al.

SCIENCE ADVANCES (2020)

Add to Collection

Article Chemistry, Physical

Hydrogenation of CO2 to Methanol on a Auδ+-In2O3-x Catalyst

Ning Rui et al.

ACS CATALYSIS (2020)

Add to Collection

Article Chemistry, Physical

Operando X-ray Absorption Spectroscopy Identifies a Monoclinic ZrO2:In Solid Solution as the Active Phase for the Hydrogenation of CO2 to Methanol

Athanasia Tsoukalou et al.

ACS CATALYSIS (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Strong Electronic Oxide-Support Interaction over In2O3/ZrO2 for Highly Selective CO2 Hydrogenation to Methanol

Chengsheng Yang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Highly Selective Hydrogenation of CO2 to Ethanol via Designed Bifunctional Ir1-In2O3 Single-Atom Catalyst

Xue Ye et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Add to Collection

Article Chemistry, Physical

Rh promoted In2O3 as a highly active catalyst for CO2 hydrogenation to methanol

Nazmul Hasan M. D. Dostagir et al.

CATALYSIS SCIENCE & TECHNOLOGY (2020)

Add to Collection

Article Chemistry, Physical

Pd Supported on MIL-68(In)-Derived In2O3 Nanotubes as Superior Catalysts to Boost CO2 Hydrogenation to Methanol

Zhongjie Cai et al.

ACS CATALYSIS (2020)

Add to Collection

Article Chemistry, Applied

Selective hydrogenation of CO2 to methanol over Ni/In2O3 catalyst

Xinyu Jia et al.

JOURNAL OF ENERGY CHEMISTRY (2020)

Add to Collection

Article Chemistry, Multidisciplinary

A highly active Pt/In2O3catalyst for CO2hydrogenation to methanol with enhanced stability

Kaihang Sun et al.

GREEN CHEMISTRY (2020)

Add to Collection

Article Engineering, Chemical

Investigation on Deactivation of Cu/ZnO/Al2O3 Catalyst for CO2 Hydrogenation to Methanol

Binglian Liang et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2019)

Add to Collection

Article Multidisciplinary Sciences

Atomic-scale engineering of indium oxide promotion by palladium for methanol production via CO2 hydrogenation

Matthias S. Frei et al.

NATURE COMMUNICATIONS (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Structural Evolution and Dynamics of an In2O3 Catalyst for CO2 Hydrogenation to Methanol: An Operando XAS-XRD and In Situ TEM Study

Athanasia Tsoukalou et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Add to Collection

Article Chemistry, Physical

Unraveling Highly Tunable Selectivity in CO2 Hydrogenation over Bimetallic In-Zr Oxide Catalysts

Tian-yuan Chen et al.

ACS CATALYSIS (2019)

Add to Collection

Article Chemistry, Physical

Direct Conversion of Syngas into Light Olefins over Zirconium-Doped Indium(III) Oxide and SAPO-34 Bifunctional Catalysts: Design of Oxide Component and Construction of Reaction Network

Junjie Su et al.

CHEMCATCHEM (2018)

Add to Collection

Article Chemistry, Multidisciplinary

DFT study of In2O3-catalyzed methanol synthesis from CO2 and CO hydrogenation on the defective site

Maobin Dou et al.

NEW JOURNAL OF CHEMISTRY (2018)

Add to Collection

Article Chemistry, Physical

Design of Interfacial Sites between Cu and Amorphous ZrO2 Dedicated to CO2-to-Methanol Hydrogenation

Shohei Tada et al.

ACS CATALYSIS (2018)

Add to Collection

Article Chemistry, Multidisciplinary

Structure-activity relationships of Cu-ZrO2 catalysts for CO2 hydrogenation to methanol: interaction effects and reaction mechanism

Yu Hao Wang et al.

RSC ADVANCES (2017)

Add to Collection

Article Chemistry, Physical

CO2 hydrogenation to methanol over Pd/In2O3: effects of Pd and oxygen vacancy

Ning Rui et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Indium Oxide as a Superior Catalyst for Methanol Synthesis by CO2 Hydrogenation

Oliver Martin et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Add to Collection

Article Chemistry, Multidisciplinary

Hydrogenation of CO2 to methanol over In2O3 catalyst

Kaihang Sun et al.

JOURNAL OF CO2 UTILIZATION (2015)

Add to Collection

Article Chemistry, Physical

Methanol synthesis from CO2 hydrogenation over a Pd4/In2O3 model catalyst: A combined DFT and kinetic study

Jingyun Ye et al.

JOURNAL OF CATALYSIS (2014)

Add to Collection

Article Chemistry, Physical

Influence of ZrO2 Structure and Copper Electronic State on Activity of Cu/ZrO2 Catalysts in Methanol Synthesis from CO2

K. Samson et al.

ACS CATALYSIS (2014)

Add to Collection

Article Chemistry, Physical

Active Oxygen Vacancy Site for Methanol Synthesis from CO2 Hydrogenation on In2O3(110): A DFT Study

Jingyun Ye et al.

ACS CATALYSIS (2013)

Add to Collection

Article Multidisciplinary Sciences

Oxygen vacancies promoting photoelectrochemical performance of In2O3 nanocubes

Jiayong Gan et al.

SCIENTIFIC REPORTS (2013)

Add to Collection

© Peeref 2019-2024. All rights reserved.