Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume -, Issue -, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202215441
Keywords
Acidic ORR Performance; FeN4 Moiety; Local Coordination Environment; Pyrolysis-Free Strategy; d-pi Conjugation Hybridization
Categories
Ask authors/readers for more resources
The traditional pyrolysis method leading to structural diversity of active sites hinders our understanding of the local coordination environment and its effects on the performance of the oxygen reduction reaction (ORR). We utilized covalent organic polymers (COPs) to define a series of FeN4 active-site configurations via a pyrolysis-free approach. Our results indicate a higher positive charge on iron atoms near an electron-withdrawing side-chain, achieved through dz2 orbital tuning in a COPBTC@Cl-CNTs catalyst, resulting in a high-valence configuration (FeH+N4). We introduced a new descriptor, xi, as the band center of iron atoms projected on the 3dz2 orbital to quantitively explain a volcano-like regulation mechanism. The catalytic performance of the COPBTC@Cl-CNTs electrocatalyst is optimized when xi is distributed between -1.887 and -1.862 eV.
The structural diversity of active sites resulting from traditional pyrolysis hinder our understanding of the local coordination environment (LCE) around the active site, and its effects on performance in the oxygen reduction reaction (ORR). We created a series of FeN4 active-site configurations via a pyrolysis-free approach where LCEs are defined by covalent organic polymers (COPs). Our results suggest a more positive charge on iron atoms in the vicinity of an electron-withdrawing side-chain; that is, a high-valence configuration (FeH+N4) that is achieved with a COPBTC@Cl-CNTs catalyst subject to dz2 ${{d}_{{z}<^>{2}}}$ -orbital tuning. A new descriptor xi, defined as the band center of iron atoms projected on the 3dz2 ${{3d}_{{z}<^>{2}}}$ -orbital, was introduced to quantitively explain a volcano-like regulation mechanism. When xi is distributed between -1.887 and -1.862 eV, the catalytic performance of the COPBTC@Cl-CNTs electrocatalyst is optimized.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available