Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 62, Issue 5, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202216089
Keywords
Aqueous Zinc-Ion; Batteries; Confined; Mechanism; Nanobelts; Vanadium Oxide
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In this study, metal ions were successfully inserted into the interlayer spacing of layered vanadium oxide nanobelts through confined synthesis, significantly improving the electrochemical performance of aqueous zinc-ion batteries.
Vanadium-based oxides with high theoretical specific capacities and open crystal structures are promising cathodes for aqueous zinc-ion batteries (AZIBs). In this work, the confined synthesis can insert metal ions into the interlayer spacing of layered vanadium oxide nanobelts without changing the original morphology. Furthermore, we obtain a series of nanomaterials based on metal-confined nanobelts, and describe the effect of interlayer spacing on the electrochemical performance. The electrochemical properties of the obtained Al2.65V6O13 center dot 2.07H(2)O as cathodes for AZIBs are remarkably improved with a high initial capacity of 571.7 mAh.g(-1) at 1.0 A g(-1). Even at a high current density of 5.0 A g(-1), the initial capacity can still reach 205.7 mAhe, with a high capacity retention of 89.2 % after 2000 cycles. This study demonstrates that nanobelts confined with metal ions can significantly improve energy storage applications, revealing new avenues for enhancing the electrochemical performance of AZIBs.
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