Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 62, Issue 6, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202216972
Keywords
Interstellar Medium; Mass Growth Processes; Polycyclic Aromatic Hydrocarbons; Radical-Radical Reactions; Reaction Mechanism
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Researchers have discovered a unconventional mechanism of reaction in which benzyl and phenyl radicals react to produce a specific isomer of the simplest polycyclic aromatic hydrocarbon (PAH), called 9H-fluorene, in the gas phase. The structure of 9H-fluorene provides fundamental insights into the evolution of hydrocarbons in high temperature settings and its potential use as a molecular building block for complex curved nanostructures.
The simplest polycyclic aromatic hydrocarbon (PAH) carrying a five-membered ring-9H-fluorene (C13H10)-is produced isomer-specifically in the gas phase by reacting benzyl (C7H7 center dot) with phenyl (C6H5 center dot) radicals in a pyrolytic reactor coupled with single photon ionization mass spectrometry. The unconventional mechanism of reaction is supported by theoretical calculations, which first produces diphenylmethane and unexpected 1-(6-methylenecyclohexa-2,4-dienyl)benzene intermediates (C13H12) accessed via addition of the phenyl radical to the ortho position of the benzyl radical. These findings offer convincing evidence for molecular mass growth processes defying conventional wisdom that radical-radical reactions are initiated through recombination at their radical centers. The structure of 9H-fluorene acts as a molecular building block for complex curved nanostructures like fullerenes and nanobowls providing fundamental insights into the hydrocarbon evolution in high temperature settings.
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