☆ 4.8 Article

On the Reactivity of Phosphaalumenes towards C-C Multiple Bonds

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

Related references

Note: Only part of the references are listed.

Article Chemistry, Multidisciplinary

Bis(1-bora-4-phosphorinane) ring closure at Cp*M (M = Fe, Co) complexes

Joseph A. Zurakowski et al.

Summary: Bis(1-bora-4-phosphorinane) metal complexes were synthesized using a Cp*M-protecting strategy and their structures were identified by NMR spectroscopy and single crystal X-ray diffraction. The synthesis of these complexes is highly dependent on the identity of the vinylphosphine precursor. This approach offers a novel method for generating saturated P,B-containing main-group ring systems.

CHEMICAL COMMUNICATIONS (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Heavier group 13/15 multiple bond systems: synthesis, structure and chemical bond activation

F. Dankert et al.

Summary: Research on heavier group 13/15 multiple bonds has shown that they are synthetically feasible, leading to the creation of new compounds such as phospha- and arsaalumenes. These findings demonstrate the obsoleteness of the traditional double bond rule and highlight the synthetic potential of these chemical bonds.

CHEMICAL COMMUNICATIONS (2022)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Selective 1,2 addition of polar X-H bonds to the Ga-P double bond of gallaphosphene L(Cl) GaPGaL

Mahendra K. Sharma et al.

Summary: Gallaphosphene reacts with polar X-H bonds at ambient temperature, showing selective 1,2 addition at the polar Ga-P double bond. The resulting complexes were characterized using IR and NMR spectroscopy, elemental analysis, and single-crystal X-ray diffraction.

DALTON TRANSACTIONS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Metathesis Reactions of a NHC-Stabilized Phosphaborene

Abhishek Koner et al.

Summary: A new N-heterocyclic carbene-stabilized phosphaborene has been synthesized and isolated, which is a room-temperature-stable crystalline solid. It exhibits remarkable reactivity and can undergo P-centre metathesis reactions.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Reactions of Tri-tert-Butylphosphatetrahedrane as a Spring-LoadedPhosphinidene Synthon Featuring Nickel-Catalyzed Transfer toUnactivated Alkenes

Martin-Louis Y. Riu et al.

Summary: Cage-opening reactions and phosphinidene transfer of highly strained tri-tert-butylphosphatetrahedrane were described. Nickel-catalyzed phosphinidene transfer to various substrates was also investigated, revealing the removable protecting ability of the tri-tert-butyl cyclopropenyl group.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Synthesis of a low-valent Al4+ cluster cation salt

Philipp Dabringhaus et al.

Summary: Low-valent aluminium compounds, which are highly reactive, have been widely studied in the field of chemistry. In this study, a method for synthesizing [Al(AlCp*)(3)](+)[Al(ORF)(4)](-) was reported, and it was found that the salt forms a dimer in the solid state and concentrated solutions.

NATURE CHEMISTRY (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Multi-Talented Gallaphosphene for Ga-P-Ga Heteroallyl Cation Generation, CO2 Storage, and C(sp3)-H Bond Activation

Mahendra K. Sharma et al.

Summary: The synthesized Gallaphosphene displayed diverse chemical properties during reactions, including different reaction pathways and products with different substrates.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Add to Collection

Article Chemistry, Multidisciplinary

A Benzodiphosphaborolediide

Kyle G. Pearce et al.

Summary: The first example of a diphosphaborolediide, benzo-fused [C6H4P2BPh](2-) (1(2-)), is prepared via a sequential lithiation approach from ortho-bis(phosphino)benzene (C6H4{PH2}) and dichlorophenylborane. The dilithio-salt can be obtained as an oligomeric THF solvate or discrete TMEDA adduct, fully characterized, and shown to exhibit some aromaticity within.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Isolable Phospha- and Arsaalumenes

Malte Fischer et al.

Summary: Combining (AlCp*)(4), a source of monomeric :AlCp* at elevated temperatures, with (Dip)TerPriPMe(3) (Pn = P, As) cleanly produces pnictaalumenes (Dip)TerPnAlCp* with polarized Pn-Al double bonds and intramolecular stabilization through interactions of Al with a flanking aryl group of the terphenyl substituent on Pn at 80 degrees C. On the other hand, using (Mes)TerPPMe(3) in reaction with 2 equiv of :AlCp* or :AlCp* results in the formation of three-membered 2 pi-aromatic ring systems (Mes)TerP(AlCpx)(2) (x = 3t, *).

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Adducts of the Parent Boraphosphaketene H2BPCO and their Decarbonylative Insertion Chemistry

Stephan Hagspiel et al.

Summary: Lewis base adducts and cyclodimers of the parent boraphosphaketene were prepared for the first time, with one adduct undergoing decarbonylation and phosphinidene insertion to form very rare 1,2-phosphaborinines, B/P isosteres of benzene. The strong donor properties of these 1,2-phosphaborinines were confirmed through synthesis of their pi complexes with Group 6 metals.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Contrasting E-H Bond Activation Pathways of a Phosphanyl-Phosphagallene

Joey Feld et al.

Summary: The reactivity of the phosphanyl-phosphagallene towards reagents with different polarity of E-H bonds shows two contrasting reaction pathways, involving frustrated Lewis pair type reactions with protic reagents and exclusive hydroelementation reactions with hydridic reagents.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Reversible and Irreversible [2+2] Cycloaddition Reactions of Heteroallenes to a Gallaphosphene

Mahendra K. Sharma et al.

Summary: The study involved cycloaddition reactions of gallaphosphene with carbodiimides and isocyanates to synthesize four-membered and six-membered metallaheterocycles, with reversible reactions confirmed. Characterization of the compounds was carried out using IR and heteronuclear NMR spectroscopy, along with elemental analysis, while quantum chemical calculations provided insights into the energetics of the reactions.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Heavier element-containing aromatics of [4n+2]-electron systems

Kei Ota et al.

Summary: This review presents the recent developments of [4n+2]-electron systems of heavier heterocycles involving group 13-15 elements, including synthesis, spectroscopic data, structural parameters, computational data, and reactivity.

CHEMICAL SOCIETY REVIEWS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

On 1,3-phosphaazaallenes and their diverse reactivity

Malte Fischer et al.

Summary: This study describes the synthesis of 1,3-phosphaazaallenes and their reactivity, including thermal stability and potential reaction products. Additionally, the reactivity of 1,3-phosphaazaallenes towards Pier's borane was investigated, revealing different reaction pathways leading to distinct products.

CHEMICAL SCIENCE (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Titanocene pnictinidene complexes

Malte Fischer et al.

Summary: The titanocene complexes with terminal phosphinidene or arsinidene ligands were synthesized using phospha-Wittig reagent and arsa-Wittig reagent, showing singlet biradicaloid characteristics in their ground state according to ab initio studies.

CHEMICAL COMMUNICATIONS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Interaction Region Indicator: A Simple Real Space Function Clearly Revealing Both Chemical Bonds and Weak Interactions

Tian Lu et al.

Summary: A new real space function IRI was proposed, which can equally well reveal chemical bonding and weak interaction regions, serving as a more complete and efficient tool compared to RDG.

CHEMISTRYMETHODS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Cycloaddition Reactions of an Active Cyclic Phosphane/Borane Pair with Alkenes, Alkynes, and Carbon Dioxide

Xiaoming Jie et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Crystalline BP-Doped Phenanthryne via Photolysis of The Elusive Boraphosphaketene

Wenlong Yang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Reactions of an Aluminum(I) Reagent with 1,2-, 1,3-, and 1,5-Dienes: Dearomatization, Reversibility, and a Pericyclic Mechanism

Clare Bakewell et al.

INORGANIC CHEMISTRY (2020)

Add to Collection

Article Chemistry, Multidisciplinary

A Phosphanyl-Phosphagallene that Functions as a Frustrated Lewis Pair

Daniel W. N. Wilson et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Pyridyl-Functionalized 1-Phosphabarrelene: Synthesis, Coordination Chemistry and Photochemical di-π-Methane Rearrangement

Marlene Bruce et al.

CHEMISTRY-A EUROPEAN JOURNAL (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Aggregation Behavior of a Six-Membered Cyclic Frustrated Phosphane/Borane Lewis Pair: Formation of a Supramolecular Cyclooctameric Macrocyclic Ring System

Xiaoming Jie et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Add to Collection

Article Chemistry, Inorganic & Nuclear

The formation of a 1,4-disilabenzene and its isomerization into a disilabenzvalene derivative

Tomohiro Sugahara et al.

DALTON TRANSACTIONS (2019)

Add to Collection

Review Chemistry, Multidisciplinary

Ambiphilic Molecules: From Organometallic Curiosity to Metal-Free Catalysts

Frederic-Georges Fontaine et al.

ACCOUNTS OF CHEMICAL RESEARCH (2018)

Add to Collection

Article Chemistry, Physical

Accurate spin-densities based on the domain-based local pair-natural orbital coupled-cluster theory

Masaaki Saitow et al.

JOURNAL OF CHEMICAL PHYSICS (2018)

Add to Collection

Review Chemistry, Multidisciplinary

The State of the Art in Azaborine Chemistry: New Synthetic Methods and Applications

Zachary X. Giustra et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Add to Collection

Article Chemistry, Inorganic & Nuclear

The selective formation of a 1,2-disilabenzene from the reaction of a disilyne with phenylacetylene

Tomohiro Sugahara et al.

DALTON TRANSACTIONS (2018)

Add to Collection

Article Chemistry, Multidisciplinary

Preparation and Characterization of P2BCh Ring Systems (Ch=S, Se) and Their Reactivity with N-Heterocyclic Carbenes

Cameron M. E. Graham et al.

CHEMISTRY-A EUROPEAN JOURNAL (2018)

Add to Collection

Article Chemistry, Physical

A new near-linear scaling, efficient and accurate, open-shell domain-based local pair natural orbital coupled cluster singles and doubles theory

Masaaki Saitow et al.

JOURNAL OF CHEMICAL PHYSICS (2017)

Add to Collection

Article Chemistry, Physical

Aluminum-phosphorus triple bonds: Do substituents make Al≡P synthetically accessible?

Jia-Syun Lu et al.

CHEMICAL PHYSICS LETTERS (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Phosphaborenes: Accessible Reagents for the Synthesis of C-C/P-B Isosteres

Amy N. Price et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Addition of alkynes to digermynes: experimental insight into the reaction pathway

Nada Y. Tashkandi et al.

DALTON TRANSACTIONS (2016)

Add to Collection

Article Chemistry, Physical

Sparse maps-A systematic infrastructure for reduced-scaling electronic structure methods. II. Linear scaling domain based pair natural orbital coupled cluster theory

Christoph Riplinger et al.

JOURNAL OF CHEMICAL PHYSICS (2016)

Add to Collection

Article Chemistry, Multidisciplinary

Diferrocenophosphaborin: A Planar-Chiral, Redox-Active and Anion-Responsive Ambiphilic Ligand

Jiawei Chen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Add to Collection

Article Chemistry, Multidisciplinary

1,2-Phosphaborines: Hybrid Inorganic/Organic P-B Analogues of Benzene

Jonathan H. Barnard et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Add to Collection

Article Chemistry, Physical

Natural triple excitations in local coupled cluster calculations with pair natural orbitals

Christoph Riplinger et al.

JOURNAL OF CHEMICAL PHYSICS (2013)

Add to Collection

Article Chemistry, Physical

An efficient and near linear scaling pair natural orbital based local coupled cluster method

Christoph Riplinger et al.

JOURNAL OF CHEMICAL PHYSICS (2013)

Add to Collection

Article Chemistry, Multidisciplinary

Synthesis, Structure, and Reactivity of a Monomeric Iminoalane

Jianfeng Li et al.

CHEMISTRY-A EUROPEAN JOURNAL (2012)

Add to Collection

Review Chemistry, Inorganic & Nuclear

Coordination-Like Chemistry of Phosphinidenes by Phosphanes

John D. Protasiewicz

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2012)

Add to Collection

Article Chemistry, Multidisciplinary

Geminal Phosphorus/Aluminum-Based Frustrated Lewis Pairs: C-H versus C equivalent to C Activation and CO2 Fixation

Christian Appelt et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

Add to Collection

Article Chemistry, Multidisciplinary

Toward Consistent Terminology for Cyclohexane Conformers in Introductory Organic Chemistry

Donna J. Nelson et al.

JOURNAL OF CHEMICAL EDUCATION (2011)

Add to Collection

Article Chemistry, Physical

Efficient and accurate local single reference correlation methods for high-spin open-shell molecules using pair natural orbitals

Andreas Hansen et al.

JOURNAL OF CHEMICAL PHYSICS (2011)

Add to Collection

Article Chemistry, Multidisciplinary

Effect of the Damping Function in Dispersion Corrected Density Functional Theory

Stefan Grimme et al.

JOURNAL OF COMPUTATIONAL CHEMISTRY (2011)

Add to Collection

Article Chemistry, Multidisciplinary

A Novel Synthetic Approach to Diaminoacetylenes: Structural Characterization and Reactivity of Aromatic and Aliphatic Ynediamines

Alex R. Petrov et al.

CHEMISTRY-A EUROPEAN JOURNAL (2010)

Add to Collection

Article Chemistry, Physical

Consistent van der Waals Radii for the Whole Main Group

Manjeera Mantina et al.

JOURNAL OF PHYSICAL CHEMISTRY A (2009)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Tuning of the optical properties and Lewis acidity of dibenzopnictogenaborins by modification on bridging main group elements

Tomohiro Agou et al.

INORGANIC CHEMISTRY (2006)

Add to Collection

Article Chemistry, Organic

Chiral phosphabarrelene ligands: Synthesis and evaluation in rhodium-catalyzed asymmetric hydrogenation

Bernhard Breit et al.

SYNTHESIS-STUTTGART (2006)

Add to Collection

Article Chemistry, Physical

Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy

F Weigend et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2005)

Add to Collection

Article Chemistry, Multidisciplinary

Phosphabarrelene-rhodium complexes as highly active catalysts for isomerization free hydroformylation of internal alkenes

B Breit et al.

CHEMICAL COMMUNICATIONS (2004)

Add to Collection

Article Chemistry, Multidisciplinary

Me2AlCH2PMe2:: A new, bifunctional cocatalyst for the Ni(II)-catalyzed oligomerization of PhSiH3

FG Fontaine et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2004)

Add to Collection

Article Chemistry, Multidisciplinary

Three different fates for phosphinidenes generated by photocleavage of phospha-Wittig reagents ArP=PMe3

S Shah et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2001)

Add to Collection

© Peeref 2019-2024. All rights reserved.