Journal
CATALYSIS COMMUNICATIONS
Volume 71, Issue -, Pages 70-73Publisher
ELSEVIER
DOI: 10.1016/j.catcom.2015.08.020
Keywords
Wang resin; (1R,2R)-(+)-1,2-DPEN; Asymmetric Michael addition; Catalytic mechanism; Fixed-bed reactor
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Funding
- National Natural Science Foundation of China [21476163]
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Wang resin was modified by (1R,2R)-(+)-1,2-DPEN by means of a triazine ring. The catalyst was characterized by thermogravimetric (TG) analysis, elemental analysis, and Fourier transform infrared spectroscopy (FT-IR). Subsequently, this catalyst was employed for the asymmetric Michael addition of acetone to beta-nitrostyrene. Under optimized conditions, 76.6% of beta-nitrostyrene conversion and 82.8% enantioselectivity of Michael adduct were obtained. On the basis of the characterization of the catalyst by X-ray photoelectron spectroscopy (VS), the mechanism of catalysis was proposed. In addition, the generality of the catalyst was evaluated with Michael additions of acetone to beta-nitroolefins. Finally, the continuous reaction was realized in a fixed-bed reactor. (C) 2015 Elsevier B.V. All rights reserved.
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